Removal of tartrazine from aqueous solutions using adsorbents based on activated carbon and Moringa oleifera seeds

被引:144
作者
Reck, Isabela Maria [1 ]
Paixao, Rebecca Manesco [2 ]
Bergamasco, Rosangela [2 ]
Vieira, Marcelo Fernandes [2 ]
Salcedo Vieira, Angelica Marquetotti [3 ]
机构
[1] Univ Estadual Maringa, UEM, Postgrad Program Food Sci, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
[2] Univ Estadual Maringa, UEM, Dept Chem Engn, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
[3] Univ Estadual Maringa, UEM, Dept Food Engn, Av Colombo 5790, BR-87020900 Maringa, Parana, Brazil
关键词
Biosorbents; Tartrazine dye; Moringa oleifera; Babassu carbon; Bone carbon; METHYLENE-BLUE DYE; ADSORPTION-KINETICS; HEAVY-METALS; WASTE-WATER; PEEL WASTE; SORPTION; ISOTHERM; VIOLET; GASES;
D O I
10.1016/j.jclepro.2017.09.237
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, a new and low-cost adsorbent, obtained from the Moringa oleifera seed, was compared to activated carbons of babassu coconut (ACBC) and bone (ABC), to remove dye from aqueous solution. Brunauer-Emmet-Teller analysis, scanning electron microscopy and X-ray diffraction were used to characterize the adsorbents. Adsorption with Moringa oleifera was able to remove more than 95% of the dye, reaching a maximum capacity of 91.27 mg g(-1) at 15 degrees C. The results demonstrate that the kinetic data were well described by the models of pseudo-second order for the activated carbon of babassu coconut and pseudo-first order for both Moringa oleifera seeds and activated bone carbon. Isothermal data using the Langmuir and Freundlich equations were adjusted, with a better fit to the experimental data given by the Freundlich equation. The thermodynamic parameters show that adsorption is an endothermic process for both carbon materials and an exothermic process for the Moringa oleifera seeds. An actual wastewater assay was performed demonstrating the effectiveness of the Moringa adsorbent. This results show that Moringa oleifera seeds can be an effective alternative to the use of activated carbon for dye removal in contaminated waters, since it is a natural adsorbent and does not undergo the carbon activation processes. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:85 / 97
页数:13
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