Vapor-Liquid Equilibria of Binary Mixtures Containing 2-Butanol and Hydrocarbons at 313.15 K

被引：10

作者：

Belabbaci, Aouicha ^{[2
]}

Vilamanan, Rosa M. ^{[1
]}

Negadi, Latifa ^{[2
]}

Carmen Martin, M. ^{[1
]}

机构：

[1] Univ Valladolid, ETS Ingn Ind, Grp Termodinam & Calibrac TERMOCAL, Dept Ingn Energet & Fluido Mecan, E-47071 Valladolid, Spain

[2] Univ Abou Bekr Belkaid Tlemcen, LATA2M, Lab Thermodynam & Modelisat Mol, Tilimsen 13000, Algeria

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2012年 / 57卷 / 03期

关键词：

SUBSTITUTION HYDROCARBONS; NONPOLAR MIXTURES; TERNARY MIXTURES; PLUS; 1-HEXENE; PRESSURE DATA; ETHER MTBE; BENZENE; THERMODYNAMICS; CYCLOHEXANE; SYSTEMS;

D O I：

10.1021/je201284y

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The paper reports the isothermal vapor-liquid equilibria (VLE) of five binary mixtures containing 2-butanol + heptane, + 2,2,4-trimethylpentane, + dodecane, + cyclohexane, and + methylbenzene at 313.15 K. A static technique has been used for the measurements. Data reduction by Barker's method provides the parameters of G(E) models. The six-parameter Margules equation, Wilson, non-random two-liquid (NRTL), and universal quasichemical activity coefficient (UNIQUAC) models have been used for the correlation of the experimental data. Good results have been obtained for all. The five investigated mixtures exhibit a positive deviation from ideality, and four of them show a maximum pressure azeotrope. Only the mixture 2-butanol + dodecane does not present an azeotrope.

引用

页码：982 / 987

页数：6

共 32 条

[1] VAPOR-LIQUID-EQUILIBRIUM .4. REDUCTION OF P-X DATA FOR TERNARY-SYSTEMS
ABBOTT, MM
FLOESS, JK
WALSH, GE
VANNESS, HC
[J]. AICHE JOURNAL, 1975, 21 (01) : 72 - 76
[2] ABBOTT MM, 1975, AICHE J, V21, P62, DOI 10.1002/aic.690210107
[3] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS
ABRAMS, DS
PRAUSNITZ, JM
[J]. AICHE JOURNAL, 1975, 21 (01) : 116 - 128
[4] VAPOR-PRESSURES AND CRITICAL-TEMPERATURES AND CRITICAL PRESSURES OF SOME ALKANOIC ACIDS - C-1 TO C-10
AMBROSE, D
GHIASSEE, NB
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (05) : 505 - 519
[5] DETERMINATION OF ACTIVITY COEFFICIENTS FROM TOTAL PRESSURE MEASUREMENTS
BARKER, JA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1953, 6 (03) : 207 - 210
[6] Vapor-Liquid Equilibria of Binary Mixtures Containing 1-Butanol and Hydrocarbons at 313.15 K
Belabbaci, Aouicha
Villamanan, Rosa M.
Negadi, Latifa
Martin, Carmen M.
Kaci, Ahmed Ait
Villamanan, Miguel A.
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (01) : 114 - 119
[7] Characterization and modelling of a gasoline containing 1,1-dimethylethyl methyl ether (MTBE), diisopropyl ether (DIPE) or 1,1-dimethylpropyl methyl ether (TAME) as fuel oxygenate based on new isothermal binary vapour-liquid data
Chamorro, CR
Martín, MC
Villamañán, MA
Segovia, JJ
[J]. FLUID PHASE EQUILIBRIA, 2004, 220 (01) : 105 - 112
[8] Dymond J.H., 1980, The Virial Coefficients of Pure Gases and Mixtures
[9] Thermodynamic excess properties for binary mixtures of 1-chlorobutane with 2-butanol or 2-methyl-1-propanol
Garriga, R
Martínez, S
Pérez, P
Gracia, M
[J]. FLUID PHASE EQUILIBRIA, 2001, 181 (1-2) : 203 - 214
[10] Vapor-Liquid Equilibria in Binary Systems Formed by Cyclohexane with Alcohols
Gieryez, Pawel
Kosowski, Andrzej
Swietlik, Ryszard
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (11) : 2996 - 3001

← 1 2 3 4 →