The Importance of Electrostatic Interactions on the Conformational Behavior of Substituted 1,3-Dioxanes: The Case of 5-Phenyl-1,3-dioxane

被引：0
|
作者：
Bailey, William F. [1 ]
Lambert, Kyle M. [1 ]
机构：
[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA
来源：
STEREOCHEMISTRY AND GLOBAL CONNECTIVITY: THE LEGACY OF ERNEST L ELIEL, VOL 2 | 2017年 / 1258卷
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Seminal, fundamental investigations by Ernest Eliel's group in the 1960's and 70's of conformational equilibria in substituted 1,3-dioxanes contributed significantly to our current understanding of the etiology of stereoelectronic effects in saturated heterocyclic systems. Following Eliel's lead, we have explored the conformational behavior of 5-phenyl-1,3-dioxanes that bear remote substituents in an effort to probe the effect of the distant substituent on the conformational equilibria of such systems.
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页码：19 / 26
页数：8
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