Synthesis and crystal structure of complex [Cdq3][Cd(qH)3](ClO4)CH3OH (q=8-quinolinolate, qH=8-quilinolinol)

被引：0

作者：

Shi, JM ^{[1
]}

Zhang, X ^{[1
]}

Lu, JJ ^{[1
]}

Chen, YQ ^{[1
]}

Ma, JP ^{[1
]}

Liu, LD ^{[1
]}

机构：

[1] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 08期

关键词：

crystal structure; cadmium complex; 8-quinolinol;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mono-nuclear complex [Cdq(3)][Cd(qH)(3)](ClO4)CH3OH has been synthesized by 8-quinolinol and hydrated cadmium perchlorate in methanol solution. The crystal belongs to triclinic, space group P (1) over bar with a = 11.1449(15), b = 13.3334(18), c = 17.654(2) angstrom, alpha = 85.555(2), beta = 88.497(2), gamma = 75.681(2)degrees, V = 2534.1(6)angstrom(3), Z = 1, C110H86Cd4Cl2 N12O22, M-r = 2448.41, D-c = 1.604 g/cm(3), F(000) = 1232 and mu = 0.961 mm(-1). The structure was refined to R = 0.0387 and wR = 0.0973 for 7775 observed reflections (I > 2 sigma(I)). In this crystal there exist two independent mononuclear complexes of [Cdq(3)](-) and [Cd(qH)(3)](2+). Each cell contains two [Cdq(3)](-) anions, two [Cd-(qH)(3)](2+) cations, two ClO4- anions and two methanol molecules.

引用

页码：913 / 916

页数：4

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