FT-jet spectroscopy:: Vibrational energy transfer in N2O

被引：3

作者：

Herman, M ^{[1
]}

Didriche, K ^{[1
]}

Rizopoulos, A ^{[1
]}

Hurtmans, D ^{[1
]}

机构：

[1] Univ Libre Bruxelles, Serv Chim Quant & Photophys, B-1050 Brussels, Belgium

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 414卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2005.08.087

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A set-up combining a high resolution Fourier transform interferometer and a quadrupole mass spectrometer with a supersonic jet expansion produced thanks to a large turbomolecular pumping unit is described. A rotational temperature close to 3 K is demonstrated. Vibration-vibration energy transfer in the expansion affecting the v(2) = 1 state in N2O is monitored in the presence of various collision partners. The transfer from the v(2) = 1 state of N2O towards the quasi resonant, lower energy v(2) = 1 state of OCS is demonstrated, in particular. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：282 / 286

页数：5

共 12 条

[1] HIGH-RESOLUTION INTERFEROMETRIC FOURIER-TRANSFORM INFRARED-ABSORPTION SPECTROSCOPY IN SUPERSONIC FREE JET EXPANSIONS - CARBON-MONOXIDE, NITRIC-OXIDE, METHANE, ETHYNE, PROPYNE, AND TRIFLUOROMETHANE
AMREIN, A
QUACK, M
SCHMITT, U
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (19) : 5455 - 5466
[2] INTERMOLECULAR V-V ENERGY-TRANSFER IN THE PHOTODISSOCIATION OF WEAKLY-BOUND COMPLEXES - A NEW EXPERIMENTAL APPROACH
BOHAC, EJ
MILLER, RE
[J]. PHYSICAL REVIEW LETTERS, 1993, 71 (01) : 54 - 57
[3] FTIR free-jet set-up for the high resolution spectroscopic investigation of condensable species
Georges, R
Bonnamy, A
Benidar, A
Decroi, M
Boissoles, J
[J]. MOLECULAR PHYSICS, 2002, 100 (10) : 1551 - 1558
[4] Georges R, 1997, MOL PHYS, V90, P381, DOI 10.1080/00268979709482618
[5] High-resolution FTIR spectroscopy using a jet:: Sampling the rovibrational spectrum of 12CH4
Georges, R
Herman, M
Hilico, JC
Robert, O
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1998, 187 (01) : 13 - 20
[6] The workings of a molecular thermometer: The vibrational excitation of carbon tetrachloride by a solvent
Graham, PB
Matus, KJM
Stratt, RM
[J]. JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (11) : 5348 - 5355
[7] CONSERVATION OF THE NUCLEAR-SPIN MODIFICATION OF CH4 IN THE COOLING PROCESS BY SUPERSONIC JET EXPANSION
HEPP, M
WINNEWISSER, G
YAMADA, KMT
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1994, 164 (01) : 311 - 314
[8] High resolution Fourier transform spectroscopy of jet-cooled molecules
Herman, M
Georges, R
Hepp, M
Hurtmans, D
[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2000, 19 (02) : 277 - 325
[9] COLLISION-INDUCED STATE-TO-STATE ENERGY-TRANSFER IN PERTURBED ROVIBRATIONAL MANIFOLDS OF SMALL POLYATOMIC-MOLECULES - MECHANISTIC INSIGHTS AND OBSERVATIONS
ORR, BJ
[J]. CHEMICAL PHYSICS, 1995, 190 (2-3) : 261 - 278
[10] FTIR investigation of non-volatile molecular nanoparticles
Signorell, R
Kunzmann, MK
Suhm, MA
[J]. CHEMICAL PHYSICS LETTERS, 2000, 329 (1-2) : 52 - 60

← 1 2 →