Conductive substrates-based component tailoring via thermal conversion of metal organic framework for enhanced microwave absorption performances

被引:33
作者
Huang, Xiaogu [1 ]
Ma, Yabin [1 ]
Lai, Haoran [2 ]
Jia, Qi [3 ]
Zhu, Liyan [3 ]
Liu, Jun [3 ]
Quan, Bin [1 ]
机构
[1] Nanjing Univ Informat Sci & Technol, Sch Chem & Mat Sci, Nanjing 210044, Peoples R China
[2] Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313001, Peoples R China
[3] Army Engn Univ PLA, Coll Field Engn, Nanjing 210094, Peoples R China
基金
中国博士后科学基金;
关键词
Fe-MOF; rGO; Synergistic effect; Microwave absorption; Broad-band absorption; ELECTROMAGNETIC-WAVE ABSORPTION; MICROSPHERES; FE3O4; NANOCOMPOSITES; CONSTRUCTION; EFFICIENT; NANORODS;
D O I
10.1016/j.jcis.2021.10.137
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Component tailoring, especially for the conductive substrates-based composites, acts as a significant role in optimizing the electromagnetic (EM) parameters and improving the EM response capability. Here, Febased metal oxides modified rGO microwave absorbers with component evolution were fabricated through hydrothermal treatment and subsequent pyrolysis process. The synergistic effects of the dielectric loss (multi-relaxations) and the magnetic loss (resonance and eddy current) are found to be effective in promoting the microwave absorption property of Fex-1Ox/C/rGO absorbers. As the thermal treatment temperature reaches 500 degrees C, the as-prepared composite sample shows ideal microwave absorption performance, where the reflection loss value is -25.94 dB, and the effective bandwidth reaches 5.84 GHz at 1.9 mm. In addition, CST simulation was employed to analyze the microwave absorption capability in the actual far field. When the scattering angle is 0 degrees and 20 degrees, the radar cross section (RCS) reduction of S-500/ PEC layers is 8.11 dB m2 and 8.80 dB m2, respectively. This study exhibits the importance of component tailoring in enhancing the performances of substrates-based microwave absorption materials. (c) 2021 Elsevier Inc. All rights reserved.
引用
收藏
页码:1323 / 1333
页数:11
相关论文
共 47 条
  • [1] Preparation of magnetic composites of MIL-53(Fe) or MIL-100(Fe) via partial transformation of their framework into γ-Fe2O3
    Bezverkhyy, I.
    Popova, E.
    Geoffroy, N.
    Herbst, F.
    Bellat, J. -P.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (21) : 8141 - 8148
  • [2] Fabrication and microwave absorption of carbon nanotubes/CoFe2O4 spinel nanocomposite -: art. no. 033105
    Che, RC
    Zhi, CY
    Liang, CY
    Zhou, XG
    [J]. APPLIED PHYSICS LETTERS, 2006, 88 (03) : 1 - 3
  • [3] Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes
    Che, RC
    Peng, LM
    Duan, XF
    Chen, Q
    Liang, XL
    [J]. ADVANCED MATERIALS, 2004, 16 (05) : 401 - +
  • [4] Ultra-thin and highly flexible cellulose nanofiber/silver nanowire conductive paper for effective electromagnetic interference shielding
    Chen, Yiming
    Pang, Liang
    Li, Yang
    Luo, Heng
    Duan, Gaigai
    Mei, Changtong
    Xu, Wenhui
    Zhou, Wei
    Liu, Kunming
    Jiang, Shaohua
    [J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2020, 135
  • [5] MOF-templated controllable synthesis of α-Fe2O3 porous nanorods and their gas sensing properties
    Gao, Pingyi
    Liu, Rong
    Huang, Huihan
    Jia, Xiao
    Pan, Haibo
    [J]. RSC ADVANCES, 2016, 6 (97) : 94699 - 94705
  • [6] Multifunctional Bulk Hybrid Foam for Infrared Stealth, Thermal Insulation, and Microwave Absorption
    Gu, Weihua
    Tan, Junwen
    Chen, Jiabin
    Zhang, Zhu
    Zhao, Yue
    Yu, Jiwen
    Ji, Guangbin
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (25) : 28727 - 28737
  • [7] Integration of plasmonic effect into spindle-shaped MIL-88A(Fe): Steering charge flow for enhanced visible-light photocatalytic degradation of ibuprofen
    Huang, Wenyuan
    Jing, Chuwen
    Zhang, Xiaodong
    Tang, Mengqi
    Tang, Liang
    Wu, Minghong
    Liu, Ning
    [J]. CHEMICAL ENGINEERING JOURNAL, 2018, 349 : 603 - 612
  • [8] Design of cellular structure of graphene aerogels for electromagnetic wave absorption
    Huang, Xiaogu
    Yu, Gaoyuan
    Zhang, Yunke
    Zhang, Mingji
    Shao, Gaofeng
    [J]. CHEMICAL ENGINEERING JOURNAL, 2021, 426
  • [9] Evolution of dielectric loss-dominated electromagnetic patterns in magnetic absorbers for enhanced microwave absorption performances
    Huang, Xiaogu
    Qiao, Man
    Lu, Xiaochi
    Li, Yafei
    Ma, Yabin
    Kang, Bo
    Quan, Bin
    Ji, Guangbin
    [J]. NANO RESEARCH, 2021, 14 (11) : 4006 - 4013
  • [10] Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNTx (MXene)
    Iqbal, Aamir
    Shahzad, Faisal
    Hantanasirisakul, Kanit
    Kim, Myung-Ki
    Kwon, Jisung
    Hong, Junpyo
    Kim, Hyerim
    Kim, Daesin
    Gogotsi, Yury
    Koo, Chong Min
    [J]. SCIENCE, 2020, 369 (6502) : 446 - +