Novel palladium catalytic systems for organic transformations

被引：210
|
作者：
Nishimura, T [1 ]
Uemura, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
SYNLETT | 2004年 / 02期
关键词：
oxidation; alcohol; palladium; C-C bond cleavage; asymmetric synthesis;
D O I：
10.1055/s-2004-815412
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This article summarizes the results of our recent studies on palladium catalytic systems for the oxidation of alcohols and alkenes using molecular oxygen or air together with several successful attempts to make the system recyclable from the viewpoint of 'green and sustainable chemistry'. In addition, palladium-catalyzed novel organic transformations of tert-alcohols (mainly cyclobutanols) and cyclobutanone oximes are also presented, where beta-carbon elimination involving C-C bond cleavage is a key step, together with some of their asymmetric versions.
引用
收藏
页码：201 / 216
页数：16
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