Single-Crystal Organic Field-Effect Transistors of Naphthodifurans

被引：20

作者：

Mitsui, Chikahiko ^{[1
,2
]}

Soeda, Junshi ^{[3
]}

Miwa, Kazumoto ^{[3
]}

Shoyama, Kazutaka ^{[1
]}

Ota, Yoshinori ^{[1
]}

Tsuji, Hayato ^{[1
,4
]}

Takeya, Jun ^{[2
,3
]}

Nakamura, Eiichi ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Univ Tokyo, Dept Frontier Sci, Kashiwa, Chiba 2778561, Japan

[3] Osaka Univ, ISIR, Ibaraki, Osaka 5670047, Japan

[4] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2015年 / 88卷 / 06期

关键词：

LIGHT-EMITTING-DIODES; CONJUGATED POLYMERS; HOST MATERIAL; ELECTROCHEMICAL PROPERTIES; ELECTRONIC-PROPERTIES; MODULAR SYNTHESIS; CHARGE-TRANSPORT; HIGH-MOBILITY; SOLID-STATE; DERIVATIVES;

D O I：

10.1246/bcsj.20150033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three types of naphthodifurans (NDFs) have been designed as active organic materials in organic field-effect transistors (OFETs), and one of them, naphtho[2,1-b:6,5-b']difuran, has been found to show an excellent OFET mobility of up to 3.6 cm(2)V(-1)s(-1). Based on the crystal-packing structure and theoretical analyses, we attribute the high carrier mobility of the NDF derivatives to large intermolecular interactions and small reorganization energies. The NDF compounds show very high thermal and electrochemical stability. Together with some previous studies, the present study indicates that fused furan compounds show a performance that is equal to or better than that of the corresponding thiophene compounds.

引用

页码：776 / 783

页数：8

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