Surface characterization of esterified cellulosic fibers by XPS and FTIR spectroscopy

被引：213
|
作者：
Matuana, LM [1 ]
Balatinecz, JJ
Sodhi, RNS
Park, CB
机构：
[1] Michigan Technol Univ, Sch Forestry & Wood Prod, Houghton, MI 49931 USA
[2] Univ Toronto, Fac Forestry, Toronto, ON M5S 3B3, Canada
[3] Univ Toronto, Ctr Biomat, Toronto, ON M5S 3E3, Canada
[4] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada
来源：
WOOD SCIENCE AND TECHNOLOGY | 2001年 / 35卷 / 03期
关键词：
D O I：
10.1007/s002260100097
中图分类号：
S7 [林业];
学科分类号：
0829 ; 0907 ;
摘要：
X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy techniques were used to study the surface chemical compositions of cellulosic fibers before and after treatments. The fibers were treated with phthalic anhydride and maleated polypropylene for surface modifications. Both XPS and FTIR spectroscopy analysis indicated that chemical bonds between hydroxyl groups of cellulosic fibers and anhydride moieties of phthalic anhydride and maleated polypropylene have occurred through esterification reaction. These chemical reagents have been added to the surface of cellulosic fibers in the form of monoester, i.e., the formation of esterified cellulosic fibers bearing a pendent carboxylic group.
引用
收藏
页码：191 / 201
页数：11
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