Conversion of fructose and glucose into 5-hydroxymethylfurfural catalyzed by a solid heteropolyacid salt

被引：182
作者：
Fan, Chunyan [1 ]
Guan, Hongyu [1 ]
Zhang, Hang [1 ]
Wang, Jianghua [1 ]
Wang, Shengtian [1 ]
Wang, Xiaohong [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin Province, Peoples R China
来源：
BIOMASS & BIOENERGY | 2011年 / 35卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Fructose; Glucose; Dehydration; 5-hydroxymethylfurfural; Heterogeneous acid catalysis; 12-TUNGSTOPHOSPHORIC ACID; DEHYDRATION; EFFICIENT; BIOMASS; FUELS;
D O I：
10.1016/j.biombioe.2011.03.004
中图分类号：
S2 [农业工程];
学科分类号：
0828 ;
摘要：
A solid heteropolyacid salt Ag3PW12O40 has been used as a heterogeneous catalyst for the production of 5-hydroxymethylfurfural (HMF) from fructose and glucose. The fructose was selectively dehydrated into HMF with the HMF yield as high as 77.7% and selectivity of 93.8% within 60 min at 120 degrees C. In addition, Ag3PW12O40 also exhibited catalytic activity for conversion of glucose into HMF. Moreover, the catalyst is tolerant to high concentration feedstock and can be recycled. The results illustrate that the Ag3PW12O40 is an excellent acid and environmentally benign solid catalyst for the production of HMF from fructose and glucose. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2659 / 2665
页数：7
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