Effect of metal-support interaction on the catalytic performance of Ni/Al2O3 for selective hydrogenation of isoprene

被引：64

作者：

Wang, Rong ^{[1
]}

Li, Yonghong ^{[1
,2
]}

Shi, Ronghui ^{[1
]}

Yang, Meimei ^{[1
]}

机构：

[1] Tianjin Univ, Sch Chem Engn, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China

[2] Tianjin Univ, Natl Engn Res Ctr Distillat Technol, Tianjin 300072, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2011年 / 344卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

Nickel catalysts; Isoprene selective hydrogenation; Metal-support interaction; Coking; Active sites; HYDRATED NICKEL CHLORIDE; MIXED OXIDES; CARBON DEPOSITION; NI/SIO2; CATALYST; ACETYLENE; PALLADIUM; PROPYNE; METHANE; ALKYNES; LITHIUM;

D O I：

10.1016/j.molcata.2011.05.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of the interaction between metal and support on the performance of different phases alumina supported nickel catalysts was demonstrated in liquid phase selective hydrogenation of isoprene in simulated gasoline. Catalysts supported on gamma-Al2O3 and kappa-Al2O3 were characterized by BET, XRD. TPR, and XPS techniques. The results showed that a "surface spinel". NiAl2O4 was formed. The supported nickel ions preferentially incorporate into the tetrahedral vacancies of gamma-Al2O3 support to form SMSI (strong metal-support interaction). while WMSI (weak metal-support interaction) was formed on kappa-Al2O3 support with little tetrahedral vacancy. When there were enough hydrogenation sites, the Ni/-gamma-Al2O3 catalysts with SMSI which can resist carbon deposition, performed higher isoprene conversion, higher stability and lower selectivity than the same nickel loading Ni/kappa-Al2O3 samples with WMSI. The weak interaction had a positive effect on the formation of coke, which was mainly related to the hydrogenolytic sites, leading to main reaction with high mono-olefins selectivity with isoprene conversion decrease evidently. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：122 / 127

页数：6

共 36 条

[1] Activated takovite catalysts for partial hydrogenation of ethyne, propyne, and propadiene [J].

Abello, Sonia ;

Verboekend, Danny ;

Bridier, Blaise ;

Perez-Ramirez, Javier .

JOURNAL OF CATALYSIS, 2008, 259 (01) :85-95

[2] Highly stereoselective semihydrogenation of alkynes promoted by nickel(0) nanoparticles [J].

Alonso, F ;

Osante, M ;

Yus, M .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (03) :305-308

[3] Hydrogenation of alkynes with hydrated nickel chloride, lithium and a catalytic amount of naphthalene [J].

Alonso, F ;

Yus, M .

TETRAHEDRON LETTERS, 1997, 38 (01) :149-152

[4] Hydrogenation of olefins with hydrated nickel chloride, lithium and a catalytic amount of naphthalene [J].

Alonso, F ;

Yus, M .

TETRAHEDRON LETTERS, 1996, 37 (38) :6925-6928

[5] Highly selective hydrogenation of multiple carbon-carbon bonds promoted by nickel(0) nanoparticles [J].

Alonso, Francisco ;

Osante, Inaki ;

Yus, Miguel .

TETRAHEDRON, 2007, 63 (01) :93-102

[6] Isoprene gas phase hydrogenation catalyzed by ThNi2 and UNi2 [J].

Branco, Joaquim Badalo ;

Goncalves, Antonio Pereira ;

de Mato, Antonio Pires .

JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 465 (1-2) :361-366

[7] Partial hydrogenation of propyne over copper-based catalysts and comparison with nickel-based analogues [J].

Bridier, Blaise ;

Lopez, Nuria ;

Perez-Ramirez, Javier .

JOURNAL OF CATALYSIS, 2010, 269 (01) :80-92

[8] Selective hydrogenation of isoprene over delta-alumina-supported eggshell Pd catalysts: Particle size effects [J].

Chang, JC ;

Chou, TC .

APPLIED CATALYSIS A-GENERAL, 1997, 156 (02) :193-205

[9] Catalytic functionalities of nickel supported on different polymorphs of alumina [J].

Chary, Komandur V. R. ;

Ramana Rao, Pendyala Venkat ;

Rao, Vattikonda Venkat .

CATALYSIS COMMUNICATIONS, 2008, 9 (05) :886-893

[10] PREPARATION AND CHARACTERIZATION OF NICKEL ALUMINUM MIXED OXIDES OBTAINED BY THERMAL-DECOMPOSITION OF HYDROTALCITE-TYPE PRECURSORS [J].

CLAUSE, O ;

REBOURS, B ;

MERLEN, E ;

TRIFIRO, F ;

VACCARI, A .

JOURNAL OF CATALYSIS, 1992, 133 (01) :231-246

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