trans-diaquabis(nicotinamide-N′-)bis(4-nitrobenzoato-O)cobalt(II)

被引:52
作者
Hokelek, T [1 ]
Necefoglu, H
机构
[1] Hacettepe Univ, Dept Phys, TR-06532 Ankara, Turkey
[2] Kafkas Univ, Dept Chem, Kars, Turkey
关键词
D O I
10.1107/S0108270198004533
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title cobalt complex, [Co(C7H4NO4)(2)(C6H6N2O)(2)(H2O)(2)], is monomeric and centrosymmetric, and contains two water molecules, two 4-nitrobenzoate and two nicotinamide (NA) ligands, all acting as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with a distorted octahedral coordination completed by the pyridine N atoms of the NA ligand, at a distance of 2.134 (2) Angstrom. The water molecules are hydrogen bonded to the carboxyl O atoms [O ... O 2.634(5) Angstrom].
引用
收藏
页码:1242 / 1244
页数:3
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