Mn21Dy Cluster with a Record Magnetization Reversal Barrier for a Mixed 3d/4f Single-Molecule Magnet

被引：145

作者：

Papatriantafyllopoulou, Constantina ^{[1
]}

Wernsdorfer, Wolfgang ^{[2
]}

Abboud, Khalil A. ^{[1
]}

Christou, George ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] UJF, CNRS, Inst Louis Neel, F-38042 Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 02期

基金：

美国国家科学基金会;

关键词：

HIGH-SPIN MOLECULES; COMPLEXES; MANGANESE; HYSTERESIS; FAMILY;

D O I：

10.1021/ic102378u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A high-oxidation-state (Mn21DyIII)-Dy-III.IV cluster with an unusual structure is reported. It also possesses a record barrier to magnetization reversal for a 3d/4f single molecule magnet (SMM) and provides insight into how the full benefit of lanthanides to the mixed 3d/4f SMM field might be realized.

引用

页码：421 / 423

页数：3

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