Fabrication of titanium oxide nanotube arrays by anodic oxidation

被引：259

作者：

Zhao, JL ^{[1
]}

Wang, XH ^{[1
]}

Chen, RZ ^{[1
]}

Li, LT ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China

来源：

SOLID STATE COMMUNICATIONS | 2005年 / 134卷 / 10期

关键词：

nano-tubes; titanium oxide; anodic oxidation;

D O I：

10.1016/j.ssc.2005.02.028

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The formation of titanium oxide nanotube arrays on titanium substrates was investigated in HF electrolytes. Under optimized electrolyte and oxidation conditions, well-ordered nanotubes of titania were fabricated. Topologies of the anodized titanium change remarkably along with the changing of applied voltages, electrolyte concentration and oxidation time. Electrochemical determination and scanning electron microscope indicate the nanotubes are formed due to the competition of titania formation and dissolution under the assistance of electric Held. A possible growth mechanism has also been presented. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：705 / 710

页数：6

共 15 条

[1] INSITU RAMAN-SPECTRA OF ANODICALLY FORMED TITANIUM-DIOXIDE LAYERS IN SOLUTIONS OF H2SO4, KOH, AND HNO3 [J].

ARSOV, LD ;

KORMANN, C ;

PLIETH, W .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) :2964-2970

[2] Self-organized porous titanium oxide prepared in H2SO4/HF electrolytes [J].

Beranek, R ;

Hildebrand, H ;

Schmuki, P .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (03) :B12-B14

[3]

Chen J, 2003, CHINESE J CHEM, V21, P665

[4] Anodization of nanoimprinted titanium:: a comparison with formation of porous alumina [J].

Choi, JS ;

Wehrspohn, RB ;

Lee, J ;

Gösele, U .

ELECTROCHIMICA ACTA, 2004, 49 (16) :2645-2652

[5] Shape-controlled synthesis of nanocrystalline titania at low temperature [J].

Chu, RH ;

Yan, JC ;

Lian, SY ;

Wang, YH ;

Yan, FC ;

Chen, DW .

SOLID STATE COMMUNICATIONS, 2004, 130 (12) :789-792

[6] Titanium oxide nanotube arrays prepared by anodic oxidation [J].

Gong, D ;

Grimes, CA ;

Varghese, OK ;

Hu, WC ;

Singh, RS ;

Chen, Z ;

Dickey, EC .

JOURNAL OF MATERIALS RESEARCH, 2001, 16 (12) :3331-3334

[7] Porous alumina template based nanodevices [J].

Jain, K ;

Lakshmikumar, ST .

IETE TECHNICAL REVIEW, 2002, 19 (05) :293-306

[8]

Leach J.S.L., 1988, CORROS SCI, P2843

[9]

MOR GK, 2003, J MATER RES

[10]

OHJ, 2004, ELECTROCHEM SOLID ST, V7, pC27

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