A Tin(IV) porphyrin with two axial organometallic NCN-Pincer platinum units

被引：4

作者：

Suijkerbuijk, Bart M. J. M. ^{[1
]}

Tooke, Duncan M. ^{[1
]}

Spek, Anthony L. ^{[1
]}

Van Koten, Gerard ^{[1
]}

Gebbink, Robertus J. M. Klein ^{[1
]}

机构：

[1] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 15期

关键词：

tin; platinum; Tin(IV) porphyrin; NCN-pincer platinum(II); supramolecular building block; X-ray structure; UV/Vis spectroscopy;

D O I：

10.1002/zaac.200700400

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tin(IV) porphyrin was combined with two axial NCN-pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN-pincer platinum derived benzoic acid. The solid-state structure determined by X-ray crystallography revealed some close contacts between the pincer complexes and the meso-p-tolyl subsitutents of the porphyrin. It was shown by H-1 NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.

引用

页码：2649 / 2653

页数：5

共 36 条

[31] Synthesis of tin(IV) complexes of chlorophyll-a derivatives with two halides as axial ligands and their optical properties in solution
Kawamoto, Yuki
Kinoshita, Yusuke
Tamiaki, Hitoshi
TETRAHEDRON, 2020, 76 (08)
[32] Linear homobimetallic 4-thioacetyl-substituted NCN pincer palladium(II) and platinum(II) complexes with N-bidentate connecting units (NCN = [C6H2(CH2NMe2)2-2,6-R-4]-)
Doering, Katrin
Taher, Deeb
Walfort, Bernhard
Lutz, Martin
Spek, Anthony L.
van Klink, Gerard P. M.
van Koten, Gerard
Lang, Heinrich
INORGANICA CHIMICA ACTA, 2008, 361 (9-10) : 2731 - 2739
[33] Comparison between the two different forms of iron(IV)-oxo porphyrin and the effects of neutral axial ligand on their catalysis: A theoretical study
Sun, Yong
Hu, Xingbang
Li, Haoran
Jalbout, Abraham F.
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2011, 966 (1-3) : 62 - 69
[34] Vanadyl(IV) Porphyrin Dimers with Palladium(II) and Platinum(II) Linkages: Syntheses, Electronic Properties, and Magnetic Interactions between the Two Moieties
Appleton, Jordan L.
Le Breton, Nolwenn
Carvalho, Mary-Ambre
Weiss, Jean
Boudalis, Athanassios K.
Gourlaouen, Christophe
Choua, Sylvie
Ruppert, Romain
CRYSTAL GROWTH & DESIGN, 2023, 23 (03) : 1689 - 1696
[35] Novel fullerene-porphyrin-fullerene triad linked by metal axial coordination:: Synthesis, X-ray crystal structure, and spectroscopic characterizations of trans-bis([60]fullerenoacetato)tin(IV) porphyrin
Kim, HJ
Park, KM
Ahn, TK
Kim, SK
Kim, KS
Kim, DH
Kim, HJ
CHEMICAL COMMUNICATIONS, 2004, (22) : 2594 - 2595
[36] Comparison between the two different forms of iron(IV)-oxo porphyrin and the effects of neutral axial ligand on their catalysis: A theoretical study (vol 966, pg 62, 2011)
Sun, Yong
Hu, Xingbang
Li, Haoran
Jalbout, Abraham F.
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2011, 969 (1-3) : 83 - 84

← 1 2 3 4 →