A Tin(IV) porphyrin with two axial organometallic NCN-Pincer platinum units

被引：4

作者：

Suijkerbuijk, Bart M. J. M. ^{[1
]}

Tooke, Duncan M. ^{[1
]}

Spek, Anthony L. ^{[1
]}

Van Koten, Gerard ^{[1
]}

Gebbink, Robertus J. M. Klein ^{[1
]}

机构：

[1] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 15期

关键词：

tin; platinum; Tin(IV) porphyrin; NCN-pincer platinum(II); supramolecular building block; X-ray structure; UV/Vis spectroscopy;

D O I：

10.1002/zaac.200700400

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tin(IV) porphyrin was combined with two axial NCN-pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN-pincer platinum derived benzoic acid. The solid-state structure determined by X-ray crystallography revealed some close contacts between the pincer complexes and the meso-p-tolyl subsitutents of the porphyrin. It was shown by H-1 NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.

引用

页码：2649 / 2653

页数：5

共 36 条

[1] Catalysis of aldehyde and imine silylcyanation by platinum and palladium NCN-pincer complexes
Fossey, JS
Richards, CJ
TETRAHEDRON LETTERS, 2003, 44 (49) : 8773 - 8776
[2] Synthesis and properties of para-substituted NCN-pincer palladium and platinum complexes
Slagt, MQ
Rodríguez, G
Grutters, MMP
Gebbink, RJMK
Klopper, W
Jenneskens, LW
Lutz, M
Spek, AL
van Koten, G
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) : 1331 - 1344
[3] Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties
Batema, Guido D.
van Walree, Cornelis A.
van Klink, Gerard P. M.
Donega, Celso de Mello
Meijerink, Andries
Perez-Moreno, Javier
Clays, Koen
van Koten, Gerard
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 246 - 252
[4] Platinum NCN-pincer complexes as catalysts for carbon-carbon bond formation.
Fossey, JS
Richards, CJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U184 - U184
[5] Synthesis and characterization of bioorganometallic conjugates composed of NCN-pincer platinum(II) complexes and uracil derivatives
Moriuchi, Toshiyuki
Noguchi, Shunichi
Sakamoto, Yuki
Hirao, Toshikazu
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (05) : 1089 - 1095
[6] Synthesis and supramolecular association of immobilized NCN-pincer platinum(II) complexes on hyperbranched polyglycerol supports
Stiriba, SE
Slagt, MQ
Kautz, H
Gebbink, RJMK
Thomann, R
Frey, H
van Koten, G
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) : 1267 - 1273
[7] Synthesis of and Evidence for Electronic Communication within Heteromultimetallic Tetrakis(NCN-pincer metal)-(Metallo)porphyrin Hybrids
Suijkerbuijk, Bart M. J. M.
Tooke, Duncan M.
Lutz, Martin
Spek, Anthony L.
Jenneskens, Leonardus W.
van Koten, Gerard
Gebbink, Robertus J. M. Klein
JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (05): : 1534 - 1549
[8] Novel silica immobilized NCN-pincer palladium(II) and platinum(II) complexes: Application as Lewis acid catalysts
Mehendale, Nilesh C.
Bezemer, Chris
van Walree, Cornelis A.
Gebbink, Robertus J. M. Klein
van Koten, Gerard
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 257 (1-2) : 167 - 175
[9] Ruthenium-to-Platinum Interactions in η6,η1 NCN-Pincer Arene Heterobimetallic Complexes: An Experimental and Theoretical Study
Bonnet, Sylvestre
Siegler, Maxime A.
van Lenthe, Joop H.
Lutz, Martin
Spek, Anthony L.
van Koten, Gerard
Gebbink, Robertus J. M. Klein
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (29) : 4667 - 4677
[10] Synthetic strategies towards new para-functionalised NCN-pincer palladium(II) and platinum(II) complexes
Slagt, MQ
Gebbink, RJMK
Lutz, M
Spek, AL
van Koten, G
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (13): : 2591 - 2592

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