A Tin(IV) porphyrin with two axial organometallic NCN-Pincer platinum units

被引：4

作者：

Suijkerbuijk, Bart M. J. M. ^{[1
]}

Tooke, Duncan M. ^{[1
]}

Spek, Anthony L. ^{[1
]}

Van Koten, Gerard ^{[1
]}

Gebbink, Robertus J. M. Klein ^{[1
]}

机构：

[1] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 15期

关键词：

tin; platinum; Tin(IV) porphyrin; NCN-pincer platinum(II); supramolecular building block; X-ray structure; UV/Vis spectroscopy;

D O I：

10.1002/zaac.200700400

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tin(IV) porphyrin was combined with two axial NCN-pincer platinum(II) fragments by utilizing the oxophilicity of the apical positions on the tin atom and the acidic nature of the NCN-pincer platinum derived benzoic acid. The solid-state structure determined by X-ray crystallography revealed some close contacts between the pincer complexes and the meso-p-tolyl subsitutents of the porphyrin. It was shown by H-1 NMR spectroscopy that these close contacts were not present in solution and that this compound can potentially act as a novel building block for supramolecular architectures.

引用

页码：2649 / 2653

页数：5

共 9 条

[1] Synthesis of and Evidence for Electronic Communication within Heteromultimetallic Tetrakis(NCN-pincer metal)-(Metallo)porphyrin Hybrids
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