The Effect of the Structure of Clay and Clay Modifier on Polystyrene-Clay Nanocomposite Morphology: A Review

被引:19
作者
Akbari, Abozar [1 ]
Talebanfard, Samin [2 ]
Hassan, Azman [1 ]
机构
[1] Univ Teknol Malaysia, Fac Chem & Nat Resources Engn, Skudai, Johor Bahru, Malaysia
[2] Islamic Azad Univ, Darab Beranch, Fac Polymer Engn, Darab, Iran
关键词
Exfoliation; Intercalation; Morphology; Polystyrene; clay nanocomposite; SAXS; Structure; TEM; XRD; MODIFIED LAYERED SILICATES; MECHANICAL-PROPERTIES; DEGRADATION;
D O I
10.1080/03602559.2010.496407
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanocomposites formation brings about an enhancement of many properties for polymers. They have attracted interests since they attain significant properties with far less clay content. It is generally assumed that exfoliation nanocomposites are preferred for the greatest increases in properties, but that is not correct in flame retardency properties. In this paper the effects of different types of clays and clay modifiers on final morphology of PS/clay nanocomposites were reviewed. Clay charge density and length, bulk, polarity, functional groups and polymerizability of the clay modifier are very significant in their efficiency and final morphology of PS/Clay nanocomposite.
引用
收藏
页码:1433 / 1444
页数:12
相关论文
共 21 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]   High-throughput method for the synthesis of high performance polystyrene nanocomposites [J].
Awad, Walid H. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2006, 45 (10) :1117-1122
[3]   Polystyrene nanocomposites based on carbazole-containing surfactants [J].
Chigwada, G ;
Jiang, DD ;
Wilkie, CA .
THERMOCHIMICA ACTA, 2005, 436 (1-2) :113-121
[4]   Mechanical and hygrothermal aging study on polystyrene/organo-montmorillonite nanocomposites [J].
Chow, W. S. ;
Teoh, J. K. ;
Lim, L. Y. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2008, 47 (10) :1040-1045
[5]   Preparation and structure of highly confined intercalated polystyrene/montmorillonite nanocomposite via a two-step method [J].
Ding, C ;
Guo, BC ;
He, H ;
Jia, DM ;
Hong, HQ .
EUROPEAN POLYMER JOURNAL, 2005, 41 (08) :1781-1786
[6]   The thermal degradation of polystyrene nanocomposite [J].
Jang, BN ;
Wilkie, CA .
POLYMER, 2005, 46 (09) :2933-2942
[7]   Exfoliated poly styrene-clay nanocomposites synthesized by solvent blending with sonication [J].
Morgan, AB ;
Harris, JD .
POLYMER, 2004, 45 (26) :8695-8703
[8]   Use of acrylic based surfmers for the preparation of exfoliated polystyrene-clay nanocomposites [J].
Samakande, Austin ;
Hartmann, Patrice C. ;
Cloete, Valeska ;
Sanderson, Ronald D. .
POLYMER, 2007, 48 (06) :1490-1499
[9]   Structural and mechanical properties of polymer nanocomposites [J].
Tjong, S. C. .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2006, 53 (3-4) :73-197
[10]   Polymer melt intercalation in organically-modified layered silicates: Model predictions and experiment [J].
Vaia, RA ;
Giannelis, EP .
MACROMOLECULES, 1997, 30 (25) :8000-8009