Silver-Catalyzed Carbon Dioxide Fixation on Alkynylindoles

被引：8
|
作者：
Uema, Seiya [1 ]
Saito, Kodai [1 ]
Yamada, Tohru [1 ]
机构：
[1] Keio Univ, Dept Chem, Yokohama, Kanagawa 2238522, Japan
来源：
ORGANIC LETTERS | 2022年
关键词：
CARBOXYLATION; INDOLE; CO2;
D O I：
10.1021/acs.orglett.2c01994
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
into 2-alkynylindole derivatives was developed to afford tricyclic indoles. Carbon dioxide was selectively fixed on the N atom of the indole, and only 6-endo-dig cyclization proceeded under mild reaction conditions. Carboxylation on C3 of the indole was not observed. This method was applicable for a variety of 2alkynylindoles, and the corresponding products were obtained in high yields without the production of side products.
引用
收藏
页码：4831 / 4834
页数：4
相关论文
共 50 条
  • [41] Fixation of Carbon Dioxide with Functionalized Ionic Liquids
    Yang, Jiawen
    Chen, Peibo
    Pan, Yingming
    Liang, Ying
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (11)
  • [42] Advances in the biological fixation of carbon dioxide by microalgae
    Zhang, Shuping
    Liu, Zhenrong
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2021, 96 (06) : 1475 - 1495
  • [43] Metal-Catalyzed Carboxylation of Organometallic Reagents with Carbon Dioxide
    Correa, Arkaitz
    Martin, Ruben
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (34) : 6201 - 6204
  • [44] Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide
    Hung Tran-Vu
    Daugulis, Olafs
    ACS CATALYSIS, 2013, 3 (10): : 2417 - 2420
  • [45] Electrocatalytic Fixation of Carbon Dioxide with Amines and Arylketones
    Wang, Jiawei
    Qian, Peng
    Hu, Kangfei
    Zha, Zhenggen
    Wang, Zhiyong
    CHEMELECTROCHEM, 2019, 6 (16) : 4292 - 4296
  • [46] Bowtie-Shaped Bio-Based Zwitterionic Polymer-Catalyzed Chemical Fixation of Carbon Dioxide
    Li, Linlin
    Ge, Qingmei
    Jiang, Nan
    Zhang, Yunqian
    Zhao, Wenfeng
    Cong, Hang
    ACS APPLIED POLYMER MATERIALS, 2024, 6 (17): : 10906 - 10915
  • [47] Ferredoxin as a Physiological Electron Donor for Carbon Dioxide Fixation to Formate in a Bacterial Carbon Dioxide Reductase
    Dietrich, Helge M.
    Mueller, Volker
    ACS CATALYSIS, 2023, 13 (18) : 12374 - 12382
  • [48] Carbon dioxide and methane as carbon source for the production of polyhydroxyalkanoates and concomitant carbon fixation
    Ma, Rui
    Li, Ji
    Tyagi, Rd
    Zhang, Xiaolei
    BIORESOURCE TECHNOLOGY, 2024, 391
  • [49] Nickel-Catalyzed Reductive Carboxylation of Cyclopropyl Motifs with Carbon Dioxide
    Moragas, Toni
    Martin, Ruben
    SYNTHESIS-STUTTGART, 2016, 48 (17): : 2816 - 2822
  • [50] Nucleophile assisted carbon dioxide fixation for a cleaner environment
    Redgard, Shaun
    Roodt, Andreas
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2021, 77 : C1029 - C1029
12345