Corrosion Inhibition Effect and Adsorption Activities of methanolic myrrh extract for Cu in 2 MHNO3

被引:19
作者
Al-Nami, Samar Y. [1 ]
Fouda, Abd El-Aziz S. [2 ]
机构
[1] King Khalid Univ, Sci Coll Girls, Chem Dept, Abha, Saudi Arabia
[2] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt
关键词
Myrrh extracts; corrosion inhibition; Cu; nitric acid; adsorption; SCHIFF-BASE COMPOUNDS; MILD-STEEL; COPPER CORROSION; ACID; HCL; DERIVATIVES; CHLORIDE; BRASS;
D O I
10.20964/2020.02.23
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Myrrh extract was tested as inhibitor on the corrosion of Cu in 2M HNO3 solution. These Tests were done by several procedures like weight loss procedure (WL), Potentiodynamic polarization (PL), electrochemical frequency modulation (EFM) and AC impedance spectra (EIS). The Cu surface was examined by utilizing atomic force microscope (AFM), scanning electron microscopy (SEM), Fourier transform infra-red (FT-IR) techniques. PL curves give indication that the myrrh acts as mixed type inhibitor. The WL, EIS and EFM results displayed that the inhibition efficiency (%IE) rise with myrrh concentration achieving 91.8% at 300 ppm, while it lowered by raising the temperature. Therefore, the results indicate that Myrrh extract has potential to be a corrosion inhibitor for Cu in acidic environment. The Langmuir adsorption isotherm agreed with the obtained results from WL method. Finally, it was found that the obtained results from several techniques are in approximately agreement.
引用
收藏
页码:1187 / 1205
页数:19
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