Transformations of allyl bromides of the adamantane series in the Ritter reaction

被引：13
作者：
Leonova, M. V. [1 ]
Baimuratov, M. R. [1 ]
Klimochkin, Yu N. [1 ]
机构：
[1] Samara State Tech Univ, Samara 443100, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 51卷 / 01期
关键词：
MEDICINAL CHEMISTRY; GAMMA-SULTONES; CAGE COMPOUNDS; DERIVATIVES; ACIDS; CARBOCATIONS; CRYSTAL; CATION;
D O I：
10.1134/S1070428015010054
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The nature and composition of the Ritter reaction products of 1-[(1E)-3-bromoprop-1-en-1-yl]-adamantane and 1-(3-bromoprop-1-en-2-yl]adamantane are largely determined by the substrate structure, electrophilic medium, and reaction conditions. Possible reaction paths leading to both conventional Ritter reaction products and heterocyclization or skeletal rearrangement products (homoadamantane gamma-sultones) are discussed.
引用
收藏
页码：26 / 32
页数：7
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