Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions?

被引：112

作者：

Akbulatov, Azat F. ^{[1
]}

Frolova, Lyubov A. ^{[1
,2
]}

Dremova, Nadezhda N. ^{[1
]}

Zhidkov, Ivan ^{[3
]}

Martynenko, Vyacheslav M. ^{[1
]}

Tsarev, Sergey A. ^{[2
]}

Luchkin, Sergey Yu. ^{[2
]}

Kurniaev, Ernst Z. ^{[3
,4
]}

Aldoshin, Sergey M. ^{[1
]}

Stevenson, Keith J. ^{[2
]}

Troshin, Pavel A. ^{[1
,2
]}

机构：

[1] RAS, IPCP, Semenov Prospect 1, Chernogolovka 142432, Russia

[2] Skolkovo Inst Sci & Technol, Ctr Energy Sci & Technol, Nobel St 3, Moscow 143026, Russia

[3] Ural Fed Univ, Inst Phys & Technol, Mira 19 St, Ekaterinburg 620002, Russia

[4] Russian Acad Sci, Ural Branch, MN Mikheev Inst Met Phys, South Kovalevskoi 18 St, Ekaterinburg 620990, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2020年 / 11卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

INDUCED DEGRADATION; THIN-FILMS; PHOTOCHEMICAL STABILITY; THERMAL-DECOMPOSITION; CH3NH3PBI3; PEROVSKITE; IODIDE PEROVSKITE; TRANSPORT LAYERS; HYBRID; INSTABILITY; MAPBI(3);

D O I：

10.1021/acs.jpclett.9b03308

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the first systematic assessment of intrinsic photothermal stability of a large panel of complex lead halides APbX(3) incorporating different univalent cations (A = CH3NH3+, [NH2CHNH2](+), Cs+) and halogen anions (X = Br, I) using a series of analytical techniques such as UV-vis and X-ray photoelectron spectroscopy, X-ray diffraction, EDX analysis, atomic force and scanning electron microscopy, ESR spectroscopy, and mass spectrometry. We show that heat stress and light soaking induce a severe degradation of perovskite films even in the absence of oxygen and moisture. The stability of complex lead halides increases in the order MAPbBr(3) < MAPbI(3) < FAPhI(3) < FAPbBr(3) < CsPbI3 < CsPbBr3, thus featuring all-inorganic perovskites as the most promising absorbers for stable perovskite solar cells. An important correlation was found between the stability of the complex lead halides and the volatility of univalent cation halides incorporated in their structure. The established relationship provides useful guidelines for designing new complex metal halides with immensely improved stability.

引用

页码：333 / 339

页数：13

共 32 条

[1] Effect of temperature on light induced degradation in methylammonium lead iodide perovskite thin films and solar cells [J].

Abdelmageed, Ghada ;

Mackeen, Cameron ;

Hellier, Kaitlin ;

Jewell, Leila ;

Seymour, Lydia ;

Tingwald, Mark ;

Bridges, Frank ;

Zhang, Jin Z. ;

Carter, Sue .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2018, 174 :566-571

[2] Probing the Intrinsic Thermal and Photochemical Stability of Hybrid and Inorganic Lead Halide Perovskites [J].

Akbulatov, Azat F. ;

Luchkin, Sergey Yu. ;

Frolova, Lyubov A. ;

Dremova, Nadezhda N. ;

Gerasimov, Kirill L. ;

Zhidkov, Ivan S. ;

Anokhin, Denis V. ;

Kurmaev, Ernst Z. ;

Stevenson, Keith J. ;

Troshin, Pavel A. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (06) :1211-1218

[3] Impact of charge transport layers on the photochemical stability of MAPbI3 in thin films and perovskite solar cells [J].

Boldyreva, A. G. ;

Akbulatov, A. F. ;

Elnaggar, M. ;

Luchkin, S. Yu ;

Danilov, A. V. ;

Zhidkov, I. S. ;

Yamilova, O. R. ;

Fedotov, Yu S. ;

Bredikhin, S. I. ;

Kurmaev, E. Z. ;

Stevenson, K. J. ;

Troshin, P. A. .

SUSTAINABLE ENERGY & FUELS, 2019, 3 (10) :2705-2716

[4] On the Thermal and Thermodynamic (In)Stability of Methylammonium Lead Halide Perovskites [J].

Brunetti, Bruno ;

Cavallo, Carmen ;

Ciccioli, Andrea ;

Gigli, Guido ;

Latini, Alessandro .

SCIENTIFIC REPORTS, 2016, 6

[5] Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells [J].

Bryant, Daniel ;

Aristidou, Nicholas ;

Pont, Sebastian ;

Sanchez-Molina, Irene ;

Chotchunangatchaval, Thana ;

Wheeler, Scot ;

Durrant, James R. ;

Haque, Saif A. .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (05) :1655-1660

[6] Self-Healing Inside APbBr3 Halide Perovskite Crystals [J].

Ceratti, Davide Raffaele ;

Rakita, Yevgeny ;

Cremonesi, Llorenc ;

Tenne, Ron ;

Kalchenko, Vyacheslav ;

Elbaum, Michael ;

Oron, Dan ;

Potenza, Marco Alberto Carlo ;

Hodes, Gary ;

Cahen, David .

ADVANCED MATERIALS, 2018, 30 (10)

[7] Thermal and light induced surface instability of perovskite films in the photoelectron spectroscopy measurement [J].

Chen, Si ;

Du, Xiang ;

Lin, Dongxu ;

Xie, Fangyan ;

Xie, Weiguang ;

Gong, Li ;

Zhang, Weihong ;

Liu, Pengyi ;

Chen, Jian .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2018, 229 :108-113

[8] Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters [J].

Dualeh, Amalie ;

Gao, Peng ;

Seok, Sang Il ;

Nazeeruddin, Mohammad Khaja ;

Graetzel, Michael .

CHEMISTRY OF MATERIALS, 2014, 26 (21) :6160-6164

[9] The chemical origin of the p-type and n-type doping effects in the hybrid methylammonium-lead iodide (MAPbI3) perovskite solar cells [J].

Frolova, Lyubov A. ;

Dremova, Nadezhda N. ;

Troshin, Pavel A. .

CHEMICAL COMMUNICATIONS, 2015, 51 (80) :14917-14920

[10] Encapsulation of Printable Mesoscopic Perovskite Solar Cells Enables High Temperature and Long-Term Outdoor Stability [J].

Fu, Zhengyang ;

Xu, Mi ;

Sheng, Yusong ;

Yan, Zhibing ;

Meng, Jun ;

Tong, Changheng ;

Li, Da ;

Wan, Zhining ;

Ming, Yue ;

Mei, Anyi ;

Hu, Yue ;

Rong, Yaoguang ;

Han, Hongwei .

ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (16)

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