Highly efficient visible light photocatalysis of CuC2O4/TiO2 nanocomposite based on photoinduced interfacial charge transfer

被引：9

作者：

Pang, Yuhua ^{[1
]}

Zhang, Junke ^{[1
]}

Feng, Caixia ^{[1
]}

Wang, Yan ^{[2
]}

Sun, Ning ^{[3
]}

Liu, Shanhu ^{[1
]}

Wang, Simeng ^{[1
]}

Li, Hongtao ^{[1
]}

Zhao, Haiyan ^{[1
]}

Ding, Yanting ^{[1
]}

Zhang, Ling ^{[1
]}

Zhou, Yanmei ^{[1
]}

Li, Deliang ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Environm & Analyt Sci, Kaifeng 475004, Peoples R China

[2] Henan Univ, Dept Sci Res, Kaifeng 475004, Peoples R China

[3] Lawrence Berkeley Natl Lab, Berkeley, CA USA

来源：

APPLIED SURFACE SCIENCE | 2018年 / 457卷

关键词：

CuC2O4/TiO2; Visible light activity; Interfacial charge transfer; SENSITIZED SOLAR-CELLS; DIFFERENT CHEMICAL METHODS; TIO2; SURFACE; FILMS; DEGRADATION; ENHANCEMENT; ABSORPTION; DEPOSITION; ORIGIN; FUEL;

D O I：

10.1016/j.apsusc.2018.06.288

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of CuC2O4/TiO2 heterostructures with different mass ratio have been prepared via a simple precipitation method. Compared to bare P25 TiO2 and pure CuC2O4, the as-prepared CuC2O4/TiO2 exhibited superior activity and stability for the degradation of propylene under visible light. Results of X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse reflectance spectroscopy (DRS) indicated that there is an intimate interaction between CuC2O4 and P25 TiO2 nanoparticles by means of the coordination bond of 0 on the surface of TiO2 with Cu atom in CuC2O4 molecular. The strong activity of CuC2O4/TiO(2 )heterostructure is due to the interfacial charge transfer (IFCT) from the valence band of the TiO2 to the CuC2O4 nanoparticles. In addition, compared to Cu (II)/TiO2 synthesized using the same amount of CuSO4 solution, CuC2O4/TiO2 exhibited much higher visible light activity for the degradation of propylene because of higher atom ratio of Cu to Ti, more visible light absorption and stronger action between CuC2O4 and TiO2.

引用

页码：764 / 772

页数：9

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