Synthesis, structure and photoluminescence of a novel palladium(I) compound:: [Pd3(μ3-Cl)2(dppp)3][Pd2(μ2-Cl)3(PPh3)2](PPh3)2

被引：10

作者：

Luo, Geng-Geng

Huang, Rong-Bin ^{[1
]}

Lin, Li-Rong

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期

基金：

中国国家自然科学基金;

关键词：

crystal structure; palladium(I); trinuclear palladium clusters; tetrahedral geometry; photoluminescence;

D O I：

10.1016/j.inoche.2008.04.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd(PPh3)(2)Cl-2 reacts with PdCl2 and 1,3-bis(diphenylphosphine)propane (dppp) in ethanol-DMF-pyridine mixed solvent to yield a novel palladium(I) compound [Pd-3(mu(3)-Cl)(2)(dppp)(3)][Pd-2(mu(2)-Cl)(3)(PPh3)(2)](PPh3)(2). It features an isolated structure based on [Pd-3(mu(3)-Cl)(2)(dppp)(3)](+) cations having triangulo-palladium clusters and [Pd-2(mu(2)-Cl)(3)(PPh3)(2)](-) anions in which the coordination environment of palladium is an unusual tetrahedral geometry. Its photoluminescence is measured. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：818 / 821

页数：4