Silicon Thin Films as Anodes for High-Performance Lithium-Ion Batteries with Effective Stress Relaxation

被引:184
|
作者
Yu, Cunjiang [2 ]
Li, Xin [1 ]
Ma, Teng [2 ]
Rong, Jiepeng [1 ]
Zhang, Rongjun [2 ]
Shaffer, Joseph [2 ]
An, Yonghao [2 ]
Liu, Qiang [2 ]
Wei, Bingqing [1 ]
Jiang, Hanqing [2 ]
机构
[1] Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA
[2] Arizona State Univ, Sch Engn Matter Transport & Energy, Tempe, AZ 85287 USA
基金
美国国家科学基金会;
关键词
stress relaxation; silicon anodes; lithium ion batteries; soft substrates; buckling; CORE-SHELL NANOWIRES; IN-SITU MEASUREMENTS; ELECTROCHEMICAL LITHIATION; PLASTIC-DEFORMATION; CAPACITY; COMPOSITE; ELECTRODES;
D O I
10.1002/aenm.201100634
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High energy capacity Li-ion batteries using Si film anodes are found to have a long cyclic life by successful relaxation of the stress induced during lithiation and delithiation. A soft elastomer substrate in the Si anode plays a beneficial role for improved performance of the battery, which suggests a general way to solve the bottleneck problem for Si anodes.
引用
收藏
页码:68 / 73
页数:6
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