A Halogen-Bonding Catenane for Anion Recognition and Sensing

被引：172
作者：
Caballero, Antonio [1 ]
Zapata, Fabiola [1 ]
White, Nicholas G. [1 ]
Costa, Paulo J. [2 ,3 ]
Felix, Vitor [2 ,3 ]
Beer, Paul D. [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England
[2] Univ Aveiro, Dept Quim, CICECO, P-3810193 Aveiro, Portugal
[3] Univ Aveiro, Seccao Autonoma Ciencias Saude, P-3810193 Aveiro, Portugal
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 08期
关键词：
anions; catenane; halogen-bonding; molecular dynamics; supramolecular chemistry; SUPRAMOLECULAR CHEMISTRY; TEMPLATED FORMATION; PI INTERACTIONS; HYDROGEN-BONDS; AQUEOUS-MEDIA; AMINO-ACID; RECEPTORS; ROTAXANE; COMPLEXES; ACTIVATION;
D O I：
10.1002/anie.201108404
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The anion-templated synthesis of a halogen-bonding catenane, which recognizes chloride and bromide ions solely by halogen bonding, is described. The catenane's ability to optically sense halide anions using fluorescence spectroscopy is demonstrated. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1876 / 1880
页数：5
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