Conversion of glycerol to acrolein in the presence of WO3/TiO2 catalysts

被引：95

作者：

Ulgen, Arda ^{[1
]}

Hoelderich, Wolfgang F. ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, D-52074 Aachen, Germany

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 400卷 / 1-2期

关键词：

Glycerol (glycerin); Acrolein; Alcohol dehydration; Solid acid; WO3/TiO2; Sustainable technology; GAS-PHASE DEHYDRATION; SUSTAINABLE PRODUCTION; OXIDATION; ACIDS;

D O I：

10.1016/j.apcata.2011.04.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dehydration of glycerol to acrolein was performed on WO3/TiO2 catalysts in a continuous flow fixed bed reactor. A maximum of 85% acrolein selectivity was achieved at nearly complete conversion of glycerol using novel WO3/TiO2 catalysts for this particular reaction. The use of oxygen suppressed side product formation. In addition, correlations between carrier properties of titania and catalytic performance were observed. The outstanding properties of WO3/TiO2 catalyst systems for the dehydration of glycerol are revealed. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：34 / 38

页数：5

共 34 条

[1] Dehydration of glycerol in gas phase using heteropolyacid catalysts as active compounds [J].