Recent advances in adsorptive separation of ethane and ethylene by C2H6-selective MOFs and other adsorbents

被引：96

作者：

Lv, Daofei ^{[1
]}

Zhou, Pingjun ^{[1
]}

Xu, Junhao ^{[1
]}

Tu, Shi ^{[2
]}

Xu, Feng ^{[1
]}

Yan, Jian ^{[1
]}

Xi, Hongxia ^{[2
]}

Yuan, Wenbing ^{[1
]}

Fu, Qiang ^{[3
]}

Chen, Xin ^{[1
]}

Xia, Qibin ^{[2
]}

机构：

[1] Foshan Univ, Sch Environm & Chem Engn, Foshan 528000, Peoples R China

[2] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Peoples R China

[3] Sichuan Jinyuansheng New Energy Technol Co Ltd, Meishan 620010, Peoples R China

来源：

CHEMICAL ENGINEERING JOURNAL | 2022年 / 431卷

基金：

中国国家自然科学基金;

关键词：

C2H6-selective adsorbents; Metal-organic frameworks; Stability; Gas separation; METAL-ORGANIC FRAMEWORK; HIGHLY SELECTIVE SEPARATION; EFFICIENT C2H6/C2H4 SEPARATION; PORE-SPACE-PARTITION; PREFERENTIAL ADSORPTION; HIGH-CAPACITY; ETHANE/ETHYLENE SEPARATION; LIGHT-HYDROCARBONS; C-2; HYDROCARBONS; OLEFIN-PARAFFIN;

D O I：

10.1016/j.cej.2021.133208

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

C2H4 is the most important and demanded chemical raw materials. Separating C2H6 from C2H4 using C2H6trapping adsorbents to lower the energy consumption in the petrochemical industry is important but challenging. This review summarizes the research progresses on the development of C2H6-selective metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), hydrogen-bonded organic frameworks (HOFs), porous organic cages (POCs), carbon-based materials, and zeolites for C2H6/C2H4 separation. The C2H6 uptakes, C2H6/C2H4 selectivities, stability, cost, scale-up synthesis, regeneration performance and shaping of C2H6-selective MOFs are overviewed. The strategies for enhancing C2H6 uptakes, C2H6/C2H4 selectivities and moisture stability on MOFs are summarized. The mechanism underlying the preferential adsorption of C2H6 over C2H4 on different adsorbents is also highlighted. Additionally, challenges and future developments of various C2H6-selective adsorbents are discussed.

引用

页数：22

共 159 条

[1] Zeolitic Imidazole Framework (ZIF) Nanospheres for Easy Encapsulation and Controlled Release of an Anticancer Drug Doxorubicin under Different External Stimuli: A Way toward Smart Drug Delivery System [J].

Adhikari, Chandan ;

Das, Anupam ;

Chakraborty, Anjan .

MOLECULAR PHARMACEUTICS, 2015, 12 (09) :3158-3166

[2] M2(&ITm&IT-dobdc) (M &DBLBOND; Mn, Fe, Co, Ni) Metal-Organic Frameworks as Highly Selective, High-Capacity Adsorbents for Olefin/Paraffin Separations [J].

Bachman, Jonathan E. ;

Kapelewski, Matthew T. ;

Reed, Douglas A. ;

Gonzalez, Miguel I. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (43) :15363-15370

[3] Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework [J].

Baldwin, Luke A. ;

Crowe, Jonathan W. ;

Pyles, David A. ;

McGrier, Psaras L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (46) :15134-15137

[4] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[5] Molecular Sieving of Ethane from Ethylene through the Molecular Cross-Section Size Differentiation in Gallate-based Metal-Organic Frameworks [J].

Bao, Zongbi ;

Wang, Jiawei ;

Zhang, Zhiguo ;

Xing, Huabin ;

Yang, Qiwei ;

Yang, Yiwen ;

Wu, Hui ;

Krishna, Rajamani ;

Zhou, Wei ;

Chen, Banglin ;

Ren, Qilong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (49) :16020-16025

[6] Adsorption of Ethane, Ethylene, Propane, and Propylene on a Magnesium-Based Metal-Organic Framework [J].

Bao, Zongbi ;

Alnemrat, Sufian ;

Yu, Liang ;

Vasiliev, Igor ;

Ren, Qilong ;

Lu, Xiuyang ;

Deng, Shuguang .

LANGMUIR, 2011, 27 (22) :13554-13562

[7] Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene [J].

Bereciartua, Pablo J. ;

Cantin, Angel ;

Corma, Avelino ;

Jorda, Jose L. ;

Palomino, Miguel ;

Rey, Fernando ;

Valencia, Susana ;

Corcoran, Edward W., Jr. ;

Kortunov, Pavel ;

Ravikovitch, Peter I. ;

Burton, Allen ;

Yoon, Chris ;

Wang, Yu ;

Paur, Charanjit ;

Guzman, Javier ;

Bishop, Adeana R. ;

Casty, Gary L. .

SCIENCE, 2017, 358 (6366) :1068-1071

[8] Ethene/Ethane and Propene/Propane Separation via the Olefin and Paraffin Selective Metal-Organic Framework Adsorbents CPO-27 and ZIF-8 [J].

Boehme, Ulrike ;

Barth, Benjamin ;

Paula, Carolin ;

Kuhnt, Andreas ;

Schwieger, Wilhelm ;

Mundstock, Alexander ;

Caro, Juergen ;

Hartmann, Martin .

LANGMUIR, 2013, 29 (27) :8592-8600

[9] Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation [J].

Bonneau, Mickaele ;

Lavenn, Christophe ;

Ginet, Patrick ;

Otake, Ken-ichi ;

Kitagawa, Susumu .

GREEN CHEMISTRY, 2020, 22 (03) :718-724

[10] Water Stability and Adsorption in Metal-Organic Frameworks [J].

Burtch, Nicholas C. ;

Jasuja, Himanshu ;

Walton, Krista S. .

CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612

← 1 2 3 4 5 6 7 8 9 10 →