Dual Functionalized Cages in Metal-Organic Frameworks via Stepwise Postsynthetic Modification

被引：51

作者：

Li, Baiyan ^{[1
,2
]}

Ma, Dingxuan ^{[1
]}

Li, Yi ^{[1
]}

Zhang, Yiming ^{[1
]}

Li, Guanghua ^{[1
]}

Shi, Zhan ^{[1
]}

Feng, Shouhua ^{[1
]}

Zaworotko, Michael J. ^{[2
,3
]}

Ma, Shengqian ^{[2
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Univ S Florida, Dept Chem, 4202 East Fowler Ave, Tampa, FL 33620 USA

[3] Univ Limerick, Dept Chem & Environm Sci, Limerick, Ireland

来源：

CHEMISTRY OF MATERIALS | 2016年 / 28卷 / 13期

基金：

美国国家科学基金会; 中国博士后科学基金; 中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; ADSORPTION PROPERTIES; MESOPOROUS SILICA; POROUS MATERIALS; PROTECTING GROUP; ACID; CATALYSIS; STRATEGY; CRYSTAL; SITES;

D O I：

10.1021/acs.chemmater.6b01898

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The introduction of bi- or multifunctionality into different cages of metal-organic frameworks (MOFs) has been of great interest because such MOF materials can demonstrate unique properties for various applications. Herein, we report a general strategy for creating different types of functionalized cages in MOFs by exerting control of the size of cage windows. Selective cage decoration was thereby enabled in such a manner that dual functional MOFs with different types of cages and pores can be created. The resultant different pore function MOF, DPF-MOF, is illustrated as a proof of concept in MOF MIL-101-Cr. An intermediate of a cascade reaction was successfully trapped and controlled the desired reaction direction. This DPF-MOF represents a new type of platform that, by trapping intermediates during the reaction processes, enhances our fundamental understanding of reaction chemistry in porous materials.

引用

页码：4781 / 4786

页数：6

共 71 条

[41] Mohideen MIH, 2011, NAT CHEM, V3, P304, DOI [10.1038/nchem.1003, 10.1038/NCHEM.1003]
[42] From molecules to crystal engineering: Supramolecular isomerism and polymorphism in network solids
Moulton, B
Zaworotko, MJ
[J]. CHEMICAL REVIEWS, 2001, 101 (06) : 1629 - 1658
[43] Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, Patrick
Belmabkhout, Youssef
Burd, Stephen D.
Cairns, Amy J.
Luebke, Ryan
Forrest, Katherine
Pham, Tony
Ma, Shengqian
Space, Brian
Wojtas, Lukasz
Eddaoudi, Mohamed
Zaworotko, Michael J.
[J]. NATURE, 2013, 495 (7439) : 80 - 84
[44] Deconstructing the Crystal Structures of Metal-Organic Frameworks and Related Materials into Their Underlying Nets
O'Keeffe, Michael
Yaghi, Omar M.
[J]. CHEMICAL REVIEWS, 2012, 112 (02) : 675 - 702
[45] A two-in-one crystal: Uptake of two different guests into two distinct channels of a biporous coordination network
Ohmori, O
Kawano, M
Fujita, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) : 1962 - 1964
[46] CATALYSIS BY HETEROPOLY COMPOUNDS .6. THE ROLE OF THE BULK ACID SITES IN CATALYTIC REACTIONS OVER NAXH3-XPW12O40
OKUHARA, T
KASAI, A
HAYAKAWA, N
YONEDA, Y
MISONO, M
[J]. JOURNAL OF CATALYSIS, 1983, 83 (01) : 121 - 130
[47] Pazé C, 2000, LANGMUIR, V16, P8139, DOI 10.1021/la000486x
[48] Microcapsule enabled multicatalyst system
Poe, Sarah L.
Kobaslija, Muris
McQuade, D. Tyler
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) : 15586 - 15587
[49] One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation
Rasero-Almansa, Antonia M.
Corma, Avelino
Iglesias, Marta
Sanchez, Felix
[J]. CHEMCATCHEM, 2013, 5 (10) : 3092 - 3100
[50] Mesoporous Silica with Site-Isolated Amine and Phosphotungstic Acid Groups: A Solid Catalyst with Tunable Antagonistic Functions for One-Pot Tandem Reactions
Shiju, N. Raveendran
Alberts, Albert H.
Khalid, Syed
Brown, David R.
Rothenberg, Gadi
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (41) : 9615 - 9619

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