Synthesis of a new chiral nitrogen containing diselenide as a precursor for selenium electrophiles

被引:35
|
作者
Santi, C
Fragale, G
Wirth, T
机构
[1] Univ Basel, Inst Organ Chem, CH-4056 Basel, Switzerland
[2] Univ Perugia, Inst Chim Organ, I-06123 Perugia, Italy
关键词
D O I
10.1016/S0957-4166(98)00380-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of a new chiral nitrogen containing diselenide is described starting from (1S,2S)-1,2-diphenylethylendiamine. The electrophilic selenium species generated from this diselenide have been used for methoxyselenenylation reactions at room temperature with good yields and high diasteroselectivities. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3625 / 3628
页数:4
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