Synthesis of body-centered cubic carbon nanocrystals

被引:80
作者
Liu, P. [1 ]
Cui, H. [1 ]
Yang, G. W. [1 ]
机构
[1] Zhongshan Univ, State Key Lab Optoelect Mat & Technol, Inst Optoelect & Funct Composite Mat, Sch Phys Sci & Engn, Guangzhou 510275, Peoples R China
关键词
D O I
10.1021/cg7006777
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A kind of carbon nanocrystals with body-centered cubic (bcc) structure has been synthesized by using a pulsed-laser induced liquid-solid interface reaction (PLIIR). Scanning electron microscopy, Raman spectra, transmission electron microscopy with energy dispersive X-ray spectrometry, selected area electronic diffraction, and high-resolution analysis are employed to characterize the morphology, composition, and structure of the synthesized nanocrystals. The experimental analyses show that the synthesized nanocrystals are single crystals with a bee structure, the so-called C-8, which was theoretically predicted by Johnston and Hoffmann. Carbon with a bee structure has potential applications in mechanical engineering and electronics, because it is superdense and superhard. The synthesis mechanisms of bee carbon nanocrystals by PLIIR are studied.
引用
收藏
页码:581 / 586
页数:6
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