Synthesis and competency of a novel dicationic phase-transfer catalyst

被引：14

作者：

Kowtoniuk, WE ^{[1
]}

Rueffer, ME ^{[1
]}

MacFarland, DK ^{[1
]}

机构：

[1] Gettysburg Coll, Dept Chem, Gettysburg, PA 17325 USA

来源：

TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 01期

关键词：

D O I：

10.1016/j.tetasy.2003.10.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and characterization of a novel phase-transfer catalyst, 6,6' di(triethylammoniummethyl)-2,2'-dihexyloxybi-1,1'-naphthalene, are reported. Preliminary catalytic studies on the alkylation of a glycine derivative show the catalyst to be an effective phase-transfer catalyst but with no enantioselectivity. (C) 2003 Published by Elsevier Ltd.

引用

页码：151 / 154

页数：4

共 28 条

[1]

Dehmlow E. V., 1993, Phase Transfer Catalysis

[2] Novel chiral bis-dipolar 6,6'-disubstituted binaphthol derivatives for second-order nonlinear optics. Synthesis and linear and nonlinear optical properties [J].

Deussen, HJ ;

Hendrickx, E ;

Boutton, C ;

Krog, D ;

Clays, K ;

Bechgaard, K ;

Persoons, A ;

Bjornholm, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) :6841-6852

[3]

Ducry L, 1999, HELV CHIM ACTA, V82, P981, DOI 10.1002/(SICI)1522-2675(19990707)82:7<981::AID-HLCA981>3.0.CO

[4]

2-V

[5]

HAISCH P, 1995, SYNTHESIS-STUTTGART, P1251

[6]

Halle R., 2000, TETRAHEDRON LETT, V41, P643

[7] Symmetrical 4,4′,6,6′-tetraarylbinaphthyl-substituted ammonium bromide as a new, chiral phase-transfer catalyst [J].

Hashimoto, T ;

Tanaka, Y ;

Maruoka, K .

TETRAHEDRON-ASYMMETRY, 2003, 14 (12) :1599-1602

[8]

HU QS, 1995, TETRAHEDRON-ASYMMETR, V6, P2123

[9] Synthesis and application of dimeric Cinchona alkaloid phase-transfer catalysts:: α,α′-bis[O(9)-allylcinchonidinium]-o, m, or p-xylene dibromide [J].

Jew, SS ;

Jeong, BS ;

Yoo, MS ;

Huh, H ;

Park, HG .

CHEMICAL COMMUNICATIONS, 2001, (14) :1244-1245

[10]

JONES RA, 2001, Q AMMONIUM SALTS THE

← 1 2 3 →