Synthesis, Characterization and Dye Adsorption Performance of Strontium Ferrite decorated Bentonite-CoNiAl Magnetic Composite

被引:24
作者
Elkhider, Khalid H. A. [1 ]
Ihsanullah, Ihsanullah [2 ]
Zubair, Mukarram [3 ]
Manzar, Mohammad Saood [3 ]
Mu'azu, Nuhu Dalhat [3 ]
Al-Harthi, Mamdouh A. [1 ,4 ]
机构
[1] King Fahd Univ Petr & Minerals, Ctr Res Excellence Nanotechnol, Dhahran 31261, Saudi Arabia
[2] King Fahd Univ Petr & Minerals, Res Inst, Ctr Environm & Water, Dhahran 31261, Saudi Arabia
[3] Imam Abdulrahman Bin Faisal Univ, Dept Environm Engn, Coll Engn, POB 1982, Dammam 31451, Saudi Arabia
[4] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran 31261, Saudi Arabia
关键词
Strontium ferrite-bentonite-CoNiAl; Magnetic composite; Layered double hydroxides; Anionic dyes; Adsorption; LAYERED DOUBLE HYDROXIDES; HIGHLY EFFICIENT REMOVAL; AQUEOUS-SOLUTION; WASTE-WATER; METHYL-ORANGE; ORGANIC POLLUTANTS; RECENT PROGRESS; ADSORBENTS; NANOCOMPOSITES; EQUILIBRIUM;
D O I
10.1007/s13369-020-04544-0
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this study, a new magnetic adsorbent, strontium ferrite-bentonite-CoNiAl composite (SF-B-CoNiAl), was synthesized via co-precipitation technique and employed for the adsorptive removal of two anionic dyes, Eriochrome Black T (EBT) and Methyl Orange (MO) from water. The surface functionalities, structure and morphology of the new adsorbent (SF-B-CoNiAl) were evaluated via scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) surface area analysis. The batch experiments indicated that the experimental adsorption capacity of SF-B-CoNiAl was 329.61 and 219.56 mg/g for EBT and MO, respectively. Freundlich isotherm best fitted the experimental data signifying heterogeneous surface with multilayer dyes uptake. The adsorption process of anionic dyes onto SF-B-CoNiAl involves both physisorption and chemisorption. The kinetic data of MO and EBT adsorption by SF-B-CoNiAl were well described by the pseudo-second-order kinetic model. The prepared adsorbent exhibited good recyclability that demonstrates their potential for application in water purification.
引用
收藏
页码:7397 / 7408
页数:12
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