Visible light photo-and bioactivity of Ag/TiO2 nanocomposite with various silver contents

被引:89
作者
Ashkarran, Ali Akbar [1 ]
Aghigh, Seyed Mahyad [1 ]
Kavianipour, Mona [1 ]
Farahani, Neda Jalali [1 ]
机构
[1] Islamic Azad Univ, Sci & Res Branch, Plasma Phys Res Ctr, Tehran, Iran
关键词
Ag/TiO2; nanocomposite; Arc discharge; Sol-gel; Heterogeneous photocatalysis; Antibacterial activity; ELECTRICAL ARC-DISCHARGE; PHOTOCATALYTIC ACTIVITY; BACTERICIDAL ACTIVITY; ANTIBACTERIAL BEHAVIOR; ESCHERICHIA-COLI; TIO2; NANOPARTICLES; CARBON; FILMS; WATER;
D O I
10.1016/j.cap.2011.01.042
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ag/TiO2 nanocomposite with various silver contents was synthesized by combination of sol-gel and the novel arc discharge methods in liquid. The Ag/TiO2 nanoparticles were characterized by X-Ray diffraction (XRD), Brunauer Emmett Teller (BET), transmission electron microscope (TEM) and ultra violet-visible absorption spectroscopy (UV-Vis). The visible light antibacterial activities and photocatalytic properties were successfully demonstrated for the inactivation of Escherichia coli (E-coli) bacteria and Rhodamine B (Rh. B). The results revealed that the Ag/TiO2 nanoparticles extended the light absorption spectrum toward the visible region and significantly enhanced the inactivation of E-coli bacteria under visible light irradiation. 0.15 gr Ag/TiO2 nanoparticles revealed best antibacterial activity while 0.05 gr Ag/TiO2 nanoparticles exhibited highest photocatalytic efficiency. The significant enhancement in the photocatalytic activity and antibacterial properties of Ag/TiO2 nanoparticles under visible light irradiation can be ascribed to the effect of noble metal Ag by acting as electron traps in TiO2 band gap. A mechanism for photocatalytic degradation of organic pollutants and antibacterial activity over Ag/TiO2 nanoparticles was proposed based on our observations. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1048 / 1055
页数:8
相关论文
共 48 条
  • [1] Lasting antibacterial activities of Ag-TiO2/Ag/a-TiO2 nanocomposite thin film photocatalysts under solar light irradiation
    Akhavan, O.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 336 (01) : 117 - 124
  • [2] The advancements in sol-gel method of doped-TiO2 photocatalysts
    Akpan, U. G.
    Hameed, B. H.
    [J]. APPLIED CATALYSIS A-GENERAL, 2010, 375 (01) : 1 - 11
  • [3] Effect of loaded silver nanoparticles on TiO2 for photocatalytic degradation of Acid Red 88
    Anandan, S.
    Sathishkumar, Panneerselvam
    Pugazhenthiran, N.
    Madhavan, J.
    Maruthamuthu, P.
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (08) : 929 - 937
  • [4] On the Formation of TiO2 Nanoparticles Via Submerged Arc Discharge Technique: Synthesis, Characterization and Photocatalytic Properties
    Ashkarran, A. A.
    Kavianipour, M.
    Aghigh, S. M.
    Afshar, S. A. Ahmadi
    Saviz, S.
    Zad, A. Iraji
    [J]. JOURNAL OF CLUSTER SCIENCE, 2010, 21 (04) : 753 - 766
  • [5] Stability, size and optical properties of colloidal silver nanoparticles prepared by electrical arc discharge in water
    Ashkarran, A. A.
    Zad, A. Iraji
    Ahadian, M. M.
    Nezhad, M. R. Hormozi
    [J]. EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2009, 48 (01) : 10601p1 - 10601p7
  • [6] Synthesis and photocatalytic activity of WO3 nanoparticles prepared by the arc discharge method in deionized water
    Ashkarran, A. A.
    zad, A. Iraji
    Ahadian, M. M.
    Ardakani, S. A. Mahdavi
    [J]. NANOTECHNOLOGY, 2008, 19 (19)
  • [7] A novel method for synthesis of colloidal silver nanoparticles by arc discharge in liquid
    Ashkarran, Ali Akbar
    [J]. CURRENT APPLIED PHYSICS, 2010, 10 (06) : 1442 - 1447
  • [8] Photocatalytic activity of ZnO nanoparticles prepared via submerged arc discharge method
    Ashkarran, Ali Akbar
    Zad, Azam Iraji
    Mahdavi, Seyed Mohammad
    Ahadian, Mohammad Mahdi
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2010, 100 (04): : 1097 - 1102
  • [9] Photocatalytic activity of ZrO2 nanoparticles prepared by electrical arc discharge method in water
    Ashkarran, Ali Akbar
    Afshar, Seyedeh Arezoo Ahmadi
    Aghigh, Seyed Mahyad
    Kavianipour, Mona
    [J]. POLYHEDRON, 2010, 29 (04) : 1370 - 1374
  • [10] ZnO nanoparticles prepared by electrical arc discharge method in water
    Ashkarran, Ali Akbar
    Zad, Azam Iraji
    Mahdavi, Seyed Mohammad
    Ahadian, Mohammad Mahdi
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2009, 118 (01) : 6 - 8