Direct formation of propargyltin compounds via C-H activation

被引：14
|
作者：
Kavara, Ajdin [1 ]
Kampf, Jeff W. [1 ]
Holl, Mark M. Banaszak [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 13期
关键词：
D O I：
10.1021/om800132h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mixed reagent [GRAPHICS] ArI reacts with alkynes to give primary and secondary propargylic C-H activation. Alkynes tested include I-phenylpropyne, 1-phenylbutyne, 1-trimethylsilylhexyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.
引用
收藏
页码：2896 / 2897
页数：2
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