Internally consistent ion volumes and their application in volume-based thermodynamics

被引：60
作者：
Glasser, Leslie
Jenkins, H. Donald Brooke
机构：
[1] Curtin Univ Technol, Dept Appl Chem, Nanochem Res Inst, Perth, WA 6845, Australia
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源：
INORGANIC CHEMISTRY | 2008年 / 47卷 / 14期
关键词：
D O I：
10.1021/ic702399u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Volume-based thermodynamics (VBT) relates the thermodynamics of condensed-phase materials to their formula unit (or molecular) volumes, V-m. In order to secure the most accurate representation of these data, the volumes used are to be derived (in order of preference) from crystal structure data or from density or, in the absence of experimental data, estimated by ion-volume summation.
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收藏
页码：6195 / 6202
页数：8
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