COMSOL simulation and experimental validation of promoter geometries facilitating citric acid transport in electrodialysis

被引:19
作者
Chandra, Anusha [1 ]
Pathiwada, Darshak [1 ]
Chattopadhyay, Sujay [1 ]
机构
[1] IIT Roorkee Saharanpur Campus, Polymer & Proc Engn, Saharanpur 247001, India
关键词
Electrodialysis; Flow hydrodynamics; Twisted Tape; Vortex generator; Helical screw; Power number; SPACER-FILLED CHANNELS; ION-EXCHANGE MEMBRANES; CONCENTRATION POLARIZATION; HEAT-TRANSFER; MASS-TRANSFER; TRANSFER ENHANCEMENT; CONDUCTING SPACERS; VORTEX GENERATORS; PLATE-FIN; TUBE;
D O I
10.1016/j.cherd.2018.12.024
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Citric acid transport facilitation in electrodialysis was investigated using different flow promoter geometries e.g. rod, twisted tape (TT), rectangular winglet (RW) shape vortex generator (VG) and helical screws at four different flow rates 5, 10, 15 and 20 LPH. Flow visualization of 39 promoters (shape, spacing and orientation) were performed using 3D simulation (COMSOL Multiphysics (R) 5.3a). Based on simulation results, 14 best promoters were selected for experimental determination of ion transport and power consumption from Sherwood number, Sh and Power number, Pn respectively. With increase in flow rate and reduced spacing, Sh increased along with Pn. Mesh type TT performed better than mono layer TT but pressure drop increased. Screw promoter placed parallel to flow showed higher Sh and Pn compared to rod, VG and TT. 50% rise in Sh was noted with helical screw (d/h = 1.33, alpha = 90 degrees) relative to empty channel. 1.5 times rise in LCDs were noted with conducting TT compared to non-conducting TTs with barely 1.5% increase in Pn. LCDs with conducting TTs were 80% higher compared to empty channel. (C) 2019 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:386 / 411
页数:26
相关论文
共 46 条
[1]  
[Anonymous], 2004, ION EXCHANGE MEMBRAN
[2]   Multi-layer spacer geometries with improved mass transport [J].
Balster, J. ;
Punt, I. ;
Stamatialis, D. F. ;
Wessling, A. .
JOURNAL OF MEMBRANE SCIENCE, 2006, 282 (1-2) :351-361
[3]   Membrane with integrated spacer [J].
Balster, J. ;
Stamatialis, D. F. ;
Wessling, M. .
JOURNAL OF MEMBRANE SCIENCE, 2010, 360 (1-2) :185-189
[4]   Towards spacer free electrodialysis [J].
Balster, J. ;
Stamatialis, D. F. ;
Wessling, M. .
JOURNAL OF MEMBRANE SCIENCE, 2009, 341 (1-2) :131-138
[5]   Electrodialysis for water desalination: A critical assessment of recent developments on process fundamentals, models and applications [J].
Campione, A. ;
Gurreri, L. ;
Ciofalo, M. ;
Micale, G. ;
Tamburini, A. ;
Cipollina, A. .
DESALINATION, 2018, 434 :121-160
[6]   Physicochemical interactions of organic acids influencing microstructure and permselectivity of anion exchange membrane [J].
Chandra, Anusha ;
Bhuvanesh, E. ;
Chattopadhyay, Sujay .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2019, 560 :260-269
[7]   Surface modification of anion exchange membrane using layer-by-layer polyelectrolytes deposition facilitating monovalent organic acid transport [J].
Chandra, Anusha ;
Bhuvanesh, E. ;
Mandal, Priyabrata ;
Chattopadhyay, Sujay .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 558 :579-590
[8]   Transport hindrances with electrodialytic recovery of citric acid from solution of strong electrolytes [J].
Chandra, Anusha ;
Tadimeti, Jogi Ganesh Dattatreya ;
Chattopadhyay, Sujay .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2018, 26 (02) :278-292
[9]   Switching selectivity of carboxylic acids and associated physico-chemical changes with pH during electrodialysis of ternary mixtures [J].
Chandra, Anusha ;
Tadimeti, Jogi Ganesh Dattatreya ;
Bhuvanesh, E. ;
Pathiwada, Darshak ;
Chattopadhyay, Sujay .
SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 193 :327-344
[10]  
Comsol, 2012, COMSOL MULT US GUID