Kinetic and mechanistic study of methanol oxidation on a Pt(110) surface in alkaline media

被引：74

作者：

Tripkovic, AV ^{[1
]}

Popovic, KD ^{[1
]}

Momcilovic, JD ^{[1
]}

Drazic, DM ^{[1
]}

机构：

[1] Univ Belgrade, Inst Electrochem, ICTM, Belgrade, Yugoslavia

来源：

ELECTROCHIMICA ACTA | 1998年 / 44卷 / 6-7期

关键词：

Pt(110) electrode; methanol oxidation; alkaline solutions; OH- ion electrosorption; reaction mechanism;

D O I：

10.1016/S0013-4686(98)00216-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The comparative study of methanol oxidation on a Pt(110) surface was carried out in bicarbonate, carbonate and sodium hydroxide solutions. It was shown that OH- electrosorption precedes the oxide layer formation in sodium hydroxide solution and is coupled by HCO3- and CO32- electrosorption in the corresponding media. Adsorbed bicarbonates suppressed the methanol oxidation. The surface activity was correlated to the OHad species coverage. Coverage with 'poisoning species' formed during methanol oxidation is time dependent. The dual path mechanism for methanol oxidation on the Pt(110) surface, as well as for the other low-index planes, was proposed based on the assumptions that HCOad and OHad are reactive intermediates and that formate is the reaction product in the main path, while CO2 is a product of 'poisoning species' oxidation in a parallel reaction path. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1135 / 1145

页数：11

共 50 条

[41] Electrocatalytic Acitivity of rGO/PEDOT:PSS Nanocomposite towards Methanol Oxidation in Alkaline Media [J].

Baruah, Bhagyalakhi ;

Kumar, Ashok .

ELECTROANALYSIS, 2018, 30 (09) :2131-2144

[42] A kinetic study of methanol oxidation over SiO2 [J].

Yao, SL ;

Yang, FO ;

Shimumora, S ;

Sakurai, H ;

Tabata, K ;

Suzuki, E .

APPLIED CATALYSIS A-GENERAL, 2000, 198 (1-2) :43-50

[43] The kinetics of methanol oxidation at a Pt film electrode, a combined mass and infrared spectroscopic study [J].

Chen, Wei ;

Cai, Jun ;

Yang, Jing ;

Sartin, Matthew M. ;

Chen, Yan-Xia .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2017, 800 :89-98

[44] The extended Stober method for synthesizing nitrogen-doped porous carbon nanospheres supported Pt nanoparticles towards methanol oxidation in alkaline media [J].

Xu, Minghao ;

Zhang, Wei ;

Qu, Yongfang ;

Liu, Xuejun ;

Zhai, Cuiping ;

Liu, Yong .

MATERIALS LETTERS, 2022, 325

[45] Synthesized colloidal-supported Pt and bimetallic Pt-Mo nanoparticles as electrocatalyst in oxidation of methanol in alkaline solution [J].

Sharma, Aarti ;

Mehta, Surinder K. ;

Singh, Sukhjinder ;

Gupta, Sakshi .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2016, 46 (01) :27-38

[46] Oxidation of the drug tiopronin by Cerium(IV) in perchloric acid media: Kinetic and mechanistic analyses [J].

Shen, Shigang ;

Chi, Xueru ;

Dong, Jingran ;

Huo, Shuying ;

Tian, Hongwu ;

Xu, Liyao ;

Shi, Tiesheng .

JOURNAL OF MOLECULAR LIQUIDS, 2017, 246 :1-6

[47] Enhanced Electrochemical Properties of Surface Roughed Pt Nanowire Electrocatalyst for Methanol Oxidation [J].

Ruan, Dajiang ;

Gao, Fan ;

Gu, Zhiyong .

ELECTROCHIMICA ACTA, 2014, 147 :225-231

[48] The Effect of the Surface Composition of Ru-Pt Bimetallic Catalysts for Methanol Oxidation [J].

Garrick, Taylor R. ;

Diao, Weijian ;

Tengco, John M. ;

Stach, Eric A. ;

Senanayake, Sanjaya D. ;

Chen, Donna A. ;

Monnier, John R. ;

Weidner, John W. .

ELECTROCHIMICA ACTA, 2016, 195 :106-111

[49] Evidence of Local pH Changes during Ethanol Oxidation at Pt Electrodes in Alkaline Media [J].

Figueiredo, Marta C. ;

Aran-Ais, Rosa M. ;

Climent, Victor ;

Kallio, Tanja ;

Feliu, Juan M. .

CHEMELECTROCHEM, 2015, 2 (09) :1254-1258

[50] Mechanistic and Kinetic Study of Atmospheric Oxidation of Chlordane Initiated by OH Radicals [J].

Ding, Zhezheng ;

Yi, Yayi ;

Xu, Fei ;

Zhang, Qingzhu ;

Xu, Xiaoli ;

Wang, Wenxing .

LETTERS IN ORGANIC CHEMISTRY, 2019, 16 (08) :647-655

← 1 2 3 4 5 →