Toxicity, a serious concern of thermal runaway from commercial Li-ion battery

被引:228
作者
Sun, Jie [1 ]
Li, Jigang [1 ]
Zhou, Tian [1 ]
Yang, Kai [3 ]
Wei, Shouping [1 ]
Tang, Na [1 ]
Dang, Nannan [1 ]
Li, Hong [4 ]
Qiu, Xinping [2 ]
Chen, Liquan [4 ]
机构
[1] Inst NBC Def, Lab Renewable Energy & Energy Safety, POB 1048, Beijing 102205, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[3] China Elect Power Res Inst, Beijing 100192, Peoples R China
[4] Chinese Acad Sci, Inst Phys, Natl Lab Condened Mater Phys, Beijing 100190, Peoples R China
关键词
Toxicity; Thermal runaway; Li-ion batteries; Combustion products; Identification; Emergency response; CATHODE MATERIALS; LITHIUM; SAFETY; CALORIMETRY; FIRE; ELECTROLYTES; HAZARDS; CELLS; LIPF6;
D O I
10.1016/j.nanoen.2016.06.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The toxicity analysis of combustion products from commercialized Li-ion batteries was performed in this work. More than 100 emitted gaseous products are identified, most of which are hazardous to the human beings and trigger negative impact on the environment. Moreover, the states of charge of battery was found to significantly affect the types of toxic combustion products, and the 100% state of charge even led to the most serious toxicity. The relationship between the concentration of toxic combustion products and battery capacity was also investigated. Interestingly, the concentration of carbon monoxide rose up rapidly up on the increase of the capacity instead of the toxic organic products. This investigation suggests that the efforts on effective battery emergency response could be potentially simplified to achieve cost down for manufacturers. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:313 / 319
页数:7
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