Simultaneous, Selective and Highly Sensitive Voltammetric Determination of Lead, Cadmium, and Zinc via Modified Pencil Graphite Electrodes

被引：3
|
作者：
Ustabasi, Gul Sirin [1 ,2 ]
Yilmaz, Ismail [1 ]
Ozcan, Mustafa [1 ]
Cetinkaya, Ebru [3 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, Fac Sci & Letters, TR-34469 Istanbul, Turkey
[2] Mir Res & Dev, Mat & Chem Res Dept, TR-34522 Istanbul, Turkey
[3] Yildiz Tech Univ, Entrepreneurship & Incubat Ctr, Yildiz Technopk, TR-34220 Istanbul, Turkey
来源：
ELECTROANALYSIS | 2022年 / 34卷 / 08期
关键词：
Heavy metals; pencil graphite electrode; square wave anodic stripping voltammetry; BISMUTH-FILM ELECTRODES; STRIPPING VOLTAMMETRY; CARBON; COMPOSITE; SAMPLES; PB; STRATEGIES; METALS; CD(II); PB(II);
D O I：
10.1002/elan.202100512
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Pencil graphite electrode (PGE) modified with MWCNT and Bi3+ (MWCNT/Bi/PGE) was utilized in simultaneous analysis of Pb2+, Cd2+, and Zn2+. Surface and electrochemical characteristics of MWCNT/Bi/PGE were investigated via SEM, cyclic voltammetry, electrochemical impedance spectroscopy, and FTIR measurements. Even though modification with MWCNT did not improve the electroactive surface area, it significantly decreased the charge transfer resistance. Furthermore, modification with Bi3+ significantly increased the sensitivity. Finally, MWCNT/Bi/PGE exhibited the highest sensitivity and reproducibility compared to PGE and PGE modified with only MWCNT. MWCNT/Bi/PGE provided LOD values of 0.27, 0.43, and 1.63 mu g L-1, and linear ranges of 1-80, 5-80, and 10-80 mu g L-1 for Pb2+, Cd2+, and Zn2+, respectively. Proposed modification method offers effective electroanalytical performance with low time consumption and cost for the analyst.
引用
收藏
页码：1237 / 1244
页数：8
相关论文
共 50 条
  • [31] Simultaneous Anodic Adsorptive Stripping Voltammetric Determination of Luteolin and 3-Hydroxyflavone in Biological Fluids Using Renewable Pencil Graphite Electrodes
    Temerk, Yassien
    Ibrahim, Hossieny
    Schuhmann, Wolfgang
    ELECTROANALYSIS, 2019, 31 (06) : 1095 - 1103
  • [32] A nanocomposite consisting of porous graphitic carbon nitride nanosheets and oxidized multiwalled carbon nanotubes for simultaneous stripping voltammetric determination of cadmium(II), mercury(II), lead(II) and zinc(II)
    Ramalingam, Manikandan
    Ponnusamy, Vinoth Kumar
    Sangilimuthu, Sriman Narayanan
    MICROCHIMICA ACTA, 2019, 186 (02)
  • [33] First Voltammetric Determination of Karbutylate via Pencil Graphite, Glassy Carbon, and Boron-Doped Diamond Electrodes in Soil Sample
    Bilge, Selva
    Donar, Yusuf Osman
    Sinag, Ali
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2024, 171 (10)
  • [34] Individual and simultaneous determination of lead, cadmium, and zinc by anodic stripping voltammetry at a bismuth bulk electrode
    Armstrong, Kristie C.
    Tatum, Clarissa E.
    Dansby-Sparks, Royce N.
    Chambers, James Q.
    Xue, Zi-Ling
    TALANTA, 2010, 82 (02) : 675 - 680
  • [35] Succinamic acid functionalized PAMAM dendrimer modified pencil graphite electrodes for voltammetric and impedimetric DNA analysis
    Congur, Gulsah
    Eksin, Ece
    Mese, Fehmi
    Erdem, Arzum
    SENSORS AND ACTUATORS B-CHEMICAL, 2014, 201 : 59 - 64
  • [36] Simple, sensitive, and cost-effective voltammetric determination of salbutamol at a pencil graphite electrode modified with Nafion and functionalized multi-walled carbon nanotubes
    Dilgin, Didem Giray
    Vural, Kader
    Karakaya, Serkan
    Dilgin, Yusuf
    MONATSHEFTE FUR CHEMIE, 2024, 155 (02): : 143 - 153
  • [37] N-Doped Hollow Porous Carbon Spheres/Bismuth Hybrid Film Modified Electrodes for Sensitive Voltammetric Determination of Trace Cadmium
    Qin, Danfeng
    Wang, Le
    Gao, Sanshuang
    Wang, Ying
    Mamat, Xamxikamar
    Li, Yongtao
    Wagberg, Thomas
    Cheng, Hao
    Hu, Guangzhi
    ELECTROANALYSIS, 2018, 30 (09) : 1906 - 1912
  • [38] Two electrochemical sensors based on pencil graphite electrodes modified with azo dye and a novel Schiff base for lead and cadmium ion quantification
    Ahmed, Abdelrahman S.
    Mohamed, Mahmoud Basseem I.
    Bedair, Mahmoud A.
    El-Zomrawy, Adham A.
    Bakr, Moustafa F.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2024, 168
  • [39] Voltammetric Determination of Acrylamide Using Coal Tar Pitch Modified Pencil Graphite Electrode by SWV
    Şeyma Korkmaz
    Wael Bosnali
    İbrahim Ender Mülazımoğlu
    Ayşen Demir Mülazımoğlu
    Food Analytical Methods, 2023, 16 : 1738 - 1745
  • [40] Voltammetric Determination of Acrylamide Using Coal Tar Pitch Modified Pencil Graphite Electrode by SWV
    Korkmaz, Seyma
    Bosnali, Wael
    Mulazimoglu, Ibrahim Ender
    Mulazimoglu, Aysen Demir
    FOOD ANALYTICAL METHODS, 2023, 16 (11-12) : 1738 - 1745
12345