Non-chelation-assisted Pd-catalysed novel sp3 C-H/sp2 C-H intermolecular oxidative coupling reaction: one-pot formation of new 5 benzyl fluorenone

被引：1

作者：

Sun, Qun ^{[1
]}

Liu, Li ^{[1
]}

Jiang, Hongxia ^{[1
]}

Chen, Shu ^{[1
]}

Liu, Jianqun ^{[1
]}

机构：

[1] Jiangxi Univ Chinese Med, Key Lab Modern Preparat TCM, Minist Educ, 1688 Meiling Rd, Nanchang 330004, Jiangxi, Peoples R China

来源：

TETRAHEDRON LETTERS | 2022年 / 104卷

基金：

中国国家自然科学基金;

关键词：

Pd-catalysed; Fluorenone; sp(3) C-H/sp(2) C-H; Oxidative coupling; C(SP(3))-H BONDS; ACTIVATION; ARYLATION; FUNCTIONALIZATION; INTERMEDIATE; OLEFINATION; AROMATICS; ARENES;

D O I：

10.1016/j.tetlet.2022.154023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot formation of new 5 benzyl fluorenone has been found that was Pd-catalysed sp(3) C-H/sp(3) C-H intermolecular oxidative coupling reaction. The condition of the new reaction was mild and rapid without chelation-assisted. This formation indicated a new way for direct coupling of benzylic C-H with aromatic C-H. (C) 2022 Elsevier Ltd. All rights reserved.

引用

页数：3

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