Novel Stable Silyl, Germyl, and Stannyl Germanium(II) Compounds Containing an Amidinato Ligand

被引：30

作者：

Matioszek, Dimitri ^{[1
]}

Katir, Nadia ^{[1
]}

Ladeira, Sonia ^{[2
]}

Castel, Annie ^{[1
]}

机构：

[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, UMR 5069, CNRS, F-31062 Toulouse 09, France

[2] Univ Toulouse 3, Struct Federat Toulousaine Chim Mol FR2599, F-31062 Toulouse 09, France

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 08期

关键词：

CRYSTAL-STRUCTURE; ACTIVE CATALYSTS; COMPLEXES; 1ST; CHEMISTRY; TRANSITION; REACTIVITY; GE; POLYMERIZATION; DERIVATIVES;

D O I：

10.1021/om200024d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the N,N'-chelated chlorogermanium(II) compound [Me3SiNC(Ph)NSiMe3]GeCl with the magnesium reagents. Mg[E(Si/Me-3)(3)](2) (E = Si, Ge, Sn) gave the new metallyl germylenes [Me3SiNC(Ph)NSiMe3]GeE(SiMe3)(3), representing the first isolated silyl- and stannylgermylenes. These compounds have been fully characterized by multinuclear NMR spectroscopy and their structures determined by X-ray diffraction analysis.

引用

页码：2230 / 2235

页数：6

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