Catalytic conversions in water. Part 10. Aerobic oxidation of terminal olefins to methyl ketones catalysed by water soluble palladium complexes

被引:60
|
作者
ten Brink, GJ [1 ]
Arends, IWCE [1 ]
Papadogianakis, G [1 ]
Sheldon, RA [1 ]
机构
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands
关键词
D O I
10.1039/a806532b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water soluble palladium(II) complexes of bidentate diamine ligands, such as bathophenanthroline disulfonate, are stable, recyclable catalysts for the selective aerobic oxidation of terminal olefins to the corresponding alkan-2-ones in a biphasic liquid-liquid system.
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页码:2359 / 2360
页数:2
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