Yb3+/Tm3+ co-doped NaNbO3 nanocrystals as three-photon-excited luminescent nanothermometers

被引:119
作者
Pereira, A. F. [1 ]
Upendra Kumar, K. [1 ]
Silva, W. F. [1 ]
Santos, W. Q. [1 ]
Jaque, D. [1 ,2 ,3 ]
Jacinto, C. [1 ]
机构
[1] Univ Fed Alagoas, Inst Fis, GFFC, BR-57072970 Maceio, AL, Brazil
[2] Univ Autonoma Madrid, Dept Fis Mat, Fluorescence Imaging Grp, E-28049 Madrid, Spain
[3] Hosp Ramon & Cajal, Inst Ramon y Cajal Invest Sanitaria, E-28034 Madrid, Spain
关键词
Nanosensor; Nanothermometry; Photo-thermal agent; Nanobiophotonics; UP-CONVERSION LUMINESCENCE; OPTICAL-TEMPERATURE SENSOR; NANOPARTICLES; EMISSION; THERMOMETRY; LANTHANIDE; DEPENDENCE; CELLS; ER3+;
D O I
10.1016/j.snb.2015.01.136
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper we report on Thulium/Ytterbium codoped sodium niobate (NaNbO3) colloidal nanocrystals as high resolution luminescent nanothermometers operating under three-photon excitation. The spectral shape of the Thulium ((1)G(4)-> H-3(6)) luminescence band at 480 nm after 980 nm (Ytterbium) excitation has been analyzed in detail in the biophysical temperature range. It has been found that the population redistribution among the thermally coupled stark levels could be successfully used for ratiometric thermal sensing. The thermal sensitivity of the three photon excited luminescence has been successfully used to evaluate, in a single-beam experiment, the light induced thermal loading taking place in 940 nm excited NaNbO3:Tm3+/Yb3+ nanocrystals. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:65 / 71
页数:7
相关论文
共 49 条
  • [1] Optically stimulated heating using Nd3+ doped NaYF4 colloidal near infrared nanophosphors
    Bednarkiewicz, A.
    Wawrzynczyk, D.
    Nyk, M.
    Strek, W.
    [J]. APPLIED PHYSICS B-LASERS AND OPTICS, 2011, 103 (04): : 847 - 852
  • [2] Nd:YAG Near-Infrared Luminescent Nanothermometers
    Benayas, Antonio
    del Rosal, Blanca
    Perez-Delgado, Alberto
    Santacruz-Gomez, Karla
    Jaque, Daniel
    Alonso Hirata, Gustavo
    Vetrone, Fiorenzo
    [J]. ADVANCED OPTICAL MATERIALS, 2015, 3 (05): : 687 - 694
  • [3] OPTICAL-FIBER TEMPERATURE SENSOR BASED ON UPCONVERSION-EXCITED FLUORESCENCE
    BERTHOU, H
    JORGENSEN, CK
    [J]. OPTICS LETTERS, 1990, 15 (19) : 1100 - 1102
  • [4] Thermometry at the nanoscale
    Brites, Carlos D. S.
    Lima, Patricia P.
    Silva, Nuno J. O.
    Millan, Angel
    Amaral, Vitor S.
    Palacio, Fernando
    Carlos, Luis D.
    [J]. NANOSCALE, 2012, 4 (16) : 4799 - 4829
  • [5] Multiphoton upconversion in rare earth doped nanocrystals for sub-diffractive microscopy
    Caillat, L.
    Hajj, B.
    Shynkar, V.
    Michely, L.
    Chauvat, D.
    Zyss, J.
    Pelle, F.
    [J]. APPLIED PHYSICS LETTERS, 2013, 102 (14)
  • [6] Intratumoral Thermal Reading During Photo-Thermal Therapy by Multifunctional Fluorescent Nanoparticles
    Carrasco, Elisa
    del Rosal, Blanca
    Sanz-Rodriguez, Francisco
    Juarranz de la Fuente, Angeles
    Haro Gonzalez, Patricia
    Rocha, Ueslen
    Upendra Kumar, Kagola
    Jacinto, Carlos
    Garcia Sole, Jose
    Jaque, Daniel
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (04) : 615 - 626
  • [7] Thermal ablation of tumor cells with anti body-functionalized single-walled carbon nanotubes
    Chakravarty, Pavitra
    Marches, Radu
    Zimmerman, Neil S.
    Swafford, Austin D. -E.
    Bajaj, Pooja
    Musselman, Inga H.
    Pantano, Paul
    Draper, Rockford K.
    Vitetta, Ellen S.
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (25) : 8697 - 8702
  • [8] Temperature Sensing and In Vivo Imaging by Molybdenum Sensitized Visible Upconversion Luminescence of Rare-Earth Oxides
    Dong, Bin
    Cao, Baosheng
    He, Yangyang
    Liu, Zhuang
    Li, Zhipeng
    Feng, Zhiqing
    [J]. ADVANCED MATERIALS, 2012, 24 (15) : 1987 - 1993
  • [9] NIR-to-NIR Two-Photon Excited CaF2: Tm3+,Yb3+ Nanoparticles: Multifunctional Nanoprobes for Highly Penetrating Fluorescence Bio-Imaging
    Dong, Ning-Ning
    Pedroni, Marco
    Piccinelli, Fabio
    Conti, Giamaica
    Sbarbati, Andrea
    Enrique Ramirez-Hernandez, Juan
    Martinez Maestro, Laura
    Carmen Iglesias-de la Cruz, Maria
    Sanz-Rodriguez, Francisco
    Juarranz, Angeles
    Chen, Feng
    Vetrone, Fiorenzo
    Capobianco, John A.
    Garcia Sole, Jose
    Bettinelli, Marco
    Jaque, Daniel
    Speghini, Adolfo
    [J]. ACS NANO, 2011, 5 (11) : 8665 - 8671
  • [10] Efficient energy upconversion emission in Tm3+/Yb3+-codoped TeO2-based optical glasses excited at 1.064 μm
    dos Santos, PV
    Vermelho, MVD
    Gouveia, EA
    de Araújo, MT
    Gouveia-Neto, AS
    Cassanjes, FC
    Ribeiro, SJL
    Messaddeq, Y
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 90 (12) : 6550 - 6552