Comparative Study on the Formation and Oxidation-Level Control of Three-Dimensional Conductive Nanofilms for Gas Sensor Applications

被引:4
作者
Cho, Kyung Hee [1 ]
Jang, Jyongsik [1 ]
Lee, Jun Seop [2 ]
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea
[2] Gachon Univ, Dept Mat Sci & Engn, Seongnam Si 13120, Gyeonggi Do, South Korea
来源
ACS OMEGA | 2020年 / 5卷 / 06期
关键词
MICELLE SIZE; IN-SITU; TEMPERATURE; PERFORMANCE; FABRICATION; MECHANISM;
D O I
10.1021/acsomega.9b03947
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Investment in wearable monitoring systems is increasing rapidly for realizing their practical applications, for example, in medical treatment, sports, and security systems. However, existing wearable monitoring systems are designed to measure a real-time physical signal and abnormal conditions rather than harmful environmental characteristics. In this study, a flexible chemical sensor electrode based on a three-dimensional conductive nanofilm (3D CNF) is fabricated via facile polymerization with temperature control. The morphology and chemical state of the 3D CNF are modified via electrochemical doping control to increase the carrier mobility and the active surface area of the sensor electrode. The sensor electrode is highly sensitive (up to 1 ppb), selective, and stable for an analyte (NH3) at room temperature owing to the three-dimensional morphology of polypyrrole and the oxidation-level control.
引用
收藏
页码:2992 / 2999
页数:8
相关论文
共 48 条
[1]   EFFECT OF TEMPERATURE ON MICELLE SIZE OF A HOMOGENEOUS NON-IONIC DETERGENT [J].
BALMBRA, RR ;
CLUNIE, JS ;
GOODMAN, JF ;
CORKILL, JM .
TRANSACTIONS OF THE FARADAY SOCIETY, 1962, 58 (476) :1661-&
[2]   X-ray photoelectron and in situ and ex situ resonance Raman spectroscopic investigations of polythiophene overoxidation [J].
Bouabdallaoui, M. ;
Aouzal, Z. ;
Ben Jadi, S. ;
El Jaouhari, A. ;
Bazzaoui, M. ;
Levi, G. ;
Aubard, J. ;
Bazzaoui, E. A. .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2017, 21 (12) :3519-3532
[3]   Large Electrically Induced Height and Volume Changes in Poly(3,4-ethylenedioxythiophene)/Poly(styrenesulfonate) Thin Films [J].
Charrier, Dimitri S. H. ;
Janssen, Rene A. J. ;
Kemerink, Martijn .
CHEMISTRY OF MATERIALS, 2010, 22 (12) :3670-3677
[4]   Recent Developments of the Solution-Processable and Highly Conductive Polyaniline Composites for Optical and Electrochemical Applications [J].
Cho, Sunghun ;
Lee, Jun Seop ;
Joo, Hyeonseo .
POLYMERS, 2019, 11 (12)
[5]   High performance n-type Ag2Se film on nylon membrane for flexible thermoelectric power generator [J].
Ding, Yufei ;
Qiu, Yang ;
Cai, Kefeng ;
Yao, Qin ;
Chen, Song ;
Chen, Lidong ;
He, Jiaqing .
NATURE COMMUNICATIONS, 2019, 10
[6]   Quantifying Lithium Salt and Polymer Density Distributions in Nanostructured Ion-Conducting Block Polymers [J].
Gartner, Thomas E., III ;
Morris, Melody A. ;
Shelton, Cameron K. ;
Dura, Joseph A. ;
Epps, Thomas H., III .
MACROMOLECULES, 2018, 51 (05) :1917-1926
[7]   Separation detection of different circulating tumor cells in the blood using an electrochemical microfluidic channel modified with a lipid-bonded conducting polymer [J].
Gurudatt, N. G. ;
Chung, Saeromi ;
Kim, Jung-Min ;
Kim, Moo-Hyun ;
Jung, Dong-Keun ;
Han, Jin-Young ;
Shim, Yoon-Bo .
BIOSENSORS & BIOELECTRONICS, 2019, 146
[8]   Conducting polypyrrole conical nanocontainers: Formation mechanism and voltage switchable property [J].
Huang, Jiyong ;
Quan, Baogang ;
Liu, Mingjie ;
Wei, Zhixiang ;
Jiang, Lei .
MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (15) :1335-1340
[9]   Conducting polymer nanowire arrays with enhanced electrochemical performance [J].
Huang, Jiyong ;
Wang, Kai ;
Wei, Zhixiang .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) :1117-1121
[10]   The NH3 sensing properties of gas sensors based on aniline reduced graphene oxide [J].
Huang, Xiaolu ;
Hu, Nantao ;
Zhang, Liling ;
Wei, Liangming ;
Wei, Hao ;
Zhang, Yafei .
SYNTHETIC METALS, 2013, 185 :25-30