Crystal structure of N-benzylmethylammonium dihydrogen-monophosphate monohydrate, [C6H5CH2NH2CH3]H2PO4•H2O

被引：13

作者：

Elaoud, Z

Kamoun, S

Jaud, J

Mhiri, T ^{[1
]}

机构：

[1] Fac Sci Sfax, Dept Chim, Lab Etat Solide, Sfax 3038, Tunisia

[2] ENIS, Lab Cristallochim Solide, Sfax 3038, Tunisia

[3] CNRS, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse, France

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1998年 / 28卷 / 04期

关键词：

organic phosphate; structure; nonlinear optical material;

D O I：

10.1023/A:1021861621824

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The salt N-benzylmethylammonium dihydrogenmonophosphate monohydrate is monoclinic with the following unit cell dimensions: a = 6.356(1)Angstrom, b = 8.385(7)Angstrom, c = 11.472(5)Angstrom, beta = 104.32(1)degrees, space group P2(1) with Z = 2. The structure consists of infinite parallel two-dimensional [IIO] planes built of mutually connected ions and water molecules by strong O-H ... O and N-H ... O hydrogen bonding. There are no contacts other than normal van der Waals interactions between the layers.

引用

页码：313 / 315

页数：3

共 14 条

[1]

[Anonymous], 1974, CHIMIE ANAL QUANTITA

[2] CRYSTAL-STRUCTURE AND PHASE-TRANSITIONS IN BETA-NH3(CH2)(2)NH3HPO4 [J].