Rational Design and Engineering of Nanomaterials Derived from Prussian Blue and Its Analogs for Electrochemical Water Splitting

被引：34

作者：

Xuan, Cuijuan ^{[1
,2
]}

Zhang, Jian ^{[2
]}

Wang, Jie ^{[1
]}

Wang, Deli ^{[2
]}

机构：

[1] Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Qingdao 266109, Peoples R China

[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Hubei Key Lab Mat Chem & Serv Failure, Minist Educ,Key Lab Mat Chem Energy Convers & Sto, Wuhan 430074, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 07期

关键词：

Prussian blue and its analogs; electrochemical water splitting; hydrogen evolution reaction; oxygen evolution reaction; material engineering strategies; OXYGEN EVOLUTION REACTION; HIGH-ACTIVITY ELECTROCATALYSTS; METAL-ORGANIC FRAMEWORKS; HYDROGEN EVOLUTION; POROUS NANOCUBES; DOPED GRAPHENE; EFFICIENT; FE; NI; NANOSHEETS;

D O I：

10.1002/asia.201901721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical water splitting (EWS) is a sustainable and promising technology for producing hydrogen as an ideal energy carrier to address environmental and energy issues. Developing highly-efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is critical for increasing the efficiency of water electrolysis. Recently, nanomaterials derived from Prussian blue (PB) and its analogs (PBA) have received increasing attention in EWS applications owing to their unique composition and structure properties. In this Minireview, the latest progress of PB/PBA-derived materials for EWS is presented. Firstly, the catalyst design principles and the advantages of preparing electrocatalysts with PB/PBA as precursors are briefly introduced. Then, strategies for enhancing the electrocatalytic performance (HER, OER or overall water splitting) were discussed in detail, and the recent development and applications of PB/PBA-derived catalysts for EWS were summarized. Finally, major challenges and possible future trends related to PB/PBA-derived functional materials are proposed.

引用

页码：958 / 972

页数：15

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