Removal of ciprofloxacin from water by millimeter-sized sodium alginate/ H3PO4 activated corncob-based biochar composite beads

被引:52
作者
Chen, Jian [1 ]
Ouyang, Jinbo [1 ]
Cai, Xionghui [1 ]
Xing, Xiaohong [1 ]
Zhou, Limin [1 ]
Liu, Zhirong [1 ]
Cai, Di [2 ]
机构
[1] East China Univ Technol, Jiangxi Prov Key Lab Synthet Chem, Nanchang 330013, Jiangxi, Peoples R China
[2] Beijing Univ Chem Technol, Natl Energy Res & Dev Ctr Biorefinery, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Ciprofloxacin; Biochar; Composite beads; Phase inversion; Sorption; EFFICIENT REMOVAL; POROUS CARBON; ADSORPTION; PHARMACEUTICALS; BIOMASS;
D O I
10.1016/j.seppur.2021.119371
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The removal of ciprofloxacin (CIP) from aqueous system is of great significance for water treatment. Here, millimeter-sized sodium alginate/H3PO4 activated corncob-based biochar composite beads (SA-PB) were prepared by a facile phase inversion method. These beads were characterized with SEM, EDS, FTIR, XRD and Raman. Results showed that SA-PB beads were successfully prepared and endowed the merits from alginate and biochar. SA-PB containing 80 wt% PB (SA-PB80) exhibited excellent CIP sorption capacity, which is much higher than pure SA and those containing 20 wt% and 50 wt% PB. Kinetic results showed that the sorption process could be fitted to pseudo-second-order model. The isotherm data indicated that sorption behavior conformed to the Langmuir model. Furthermore, SA-PB exhibited high tolerance to ionic strength and favorable reusability, and SA-PB also has plentiful desirable advantages such as biodegradability, economy and easily separable for solidliquid system as well as its efficient CIP capture performance.
引用
收藏
页数:9
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