Triple-decker main group cations

被引：46

作者：

Cowley, AH ^{[1
]}

Macdonald, CLB ^{[1
]}

Silverman, JS ^{[1
]}

Gorden, JD ^{[1
]}

Voigt, A ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 02期

关键词：

D O I：

10.1039/b005425i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of the first main group triple-decker cations are described, namely, [(eta (5)-C5Me5)Sn(mu-eta (5)-C5Me5)Sn(eta (5)-C5Me5)][Ga(C6F5)(4)] and [(eta (6)-C7H8)In(mu-eta (5)-C5Me5)In(eta (6)-C7H8)][(C6F5)(3)BO(H)B(C6F5)(3)], both of which have been characterized by X-ray crystallography; the former was prepared by the reaction of Sn(eta (5)-C5Me5)(2) with Ga(C6F5)(3), while the latter was prepared by treatment of [In(eta (5)-C5Me5)](6) with an equimolar mixture of B(C6F5)(3) and H2O .B(C6F5)(3).

引用

页码：175 / 176

页数：2

共 20 条

[1] THE NEXT HOMOLOG OF THE BIS(CYCLOPENTADIENYL)THALLATE ANION - SYNTHESIS AND X-RAY STRUCTURE DETERMINATION OF [(ETA(5)-CSH5)TL(MU-C5H5)TL(ETA(5)-C5H(5))]-[LI(12-CROWN-4)(2)](+)THF
ARMSTRONG, DR
EDWARDS, AJ
MONCRIEFF, D
PAVER, MA
RAITHBY, PR
RENNIE, MA
RUSSELL, CA
WRIGHT, DS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (09) : 927 - 928
[2] (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(I) AND (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(III) COMPOUNDS - SYNTHESES, REACTIVITIES, AND X-RAY-DIFFRACTION AND ELECTRON-DIFFRACTION STUDIES OF IN(C5ME5)
BEACHLEY, OT
BLOM, R
CHURCHILL, MR
FAEGRI, K
FETTINGER, JC
PAZIK, JC
VICTORIANO, L
[J]. ORGANOMETALLICS, 1989, 8 (02) : 346 - 356
[3] Beswick MA, 1998, CHEM SOC REV, V27, P225
[4] Structural control in the formation of multidecker sandwich anions of plumbocene:: The effects of encapsulating the alkali metal counterions
Beswick, MA
Gornitzka, H
Kärcher, T
Mosquera, MEG
Palmer, JS
Raithby, PR
Russell, CA
Stalke, D
Steiner, A
Wright, DS
[J]. ORGANOMETALLICS, 1999, 18 (07) : 1148 - 1153
[5] Equilibria in the B(C6F5)3-H2O system:: synthesis and crystal structures of H2O•B(C6F5)3 and the anions [HOB(C6F5)3]- and [F5C6)3B(μ-OH)B(C6F5)3]-
Danopoulos, AA
Galsworthy, JR
Green, MLH
Cafferkey, S
Doerrer, LH
Hursthouse, MB
[J]. CHEMICAL COMMUNICATIONS, 1998, (22) : 2529 - 2530
[6] Studies of the formation and decomposition pathways for cationic zirconocene hydride silyl complexes
Dioumaev, VK
Harrod, JF
[J]. ORGANOMETALLICS, 1997, 16 (13) : 2798 - 2807
[7] Oxidation of [M(η-C5H5)2], M = Cr, Fe or Co, by the new Bronsted acid H2O•B(C6F5)3 yielding the salts [M(η-C5H5)2]+A-, where A- = [(C6F5)3B(μ-OH)B(C6F5)3]- or [(C6F5)3BOH•••H2OB(C6F5)3]-
Doerrer, LH
Green, MLH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (24): : 4325 - 4329
[8] DO SUBVALENT MAIN-GROUP COMPOUNDS FORM ADDUCTS WITH MAIN-GROUP ACCEPTORS - THE BF3 ADDUCT OF STANNOCENE, A REVISION - THE CRYSTAL AND MOLECULAR-STRUCTURE OF ([BF4]-(MU-ETA-5-C5H5)2SN[MU-ETA-5-C5H5SN]+THF)N
DORY, TS
ZUCKERMAN, JJ
BARNES, CL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 281 (01) : C1 - C7
[9] BIS(1,3,5-TRIMETHYLBENZENE)INDIUM(I) TETRABROMOINDATE(III), THE 1ST ARENE COMPLEX OF INDIUM
EBENHOCH, J
MULLER, G
RIEDE, J
SCHMIDBAUR, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (05): : 386 - 388
[10] The heaviest alkali metallocene: Structure of an anionic cesocene triple-decker
Harder, S
Prosenc, MH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01): : 97 - 99

← 1 2 →