A Review of Underwater Laser-induced Breakdown Spectroscopy of Submerged Solids

被引:33
作者
Matsumoto, Ayumu [1 ]
Sakka, Tetsuo [2 ]
机构
[1] Univ Hyogo, Grad Sch Engn, Dept Chem Engn & Mat Sci, Himeji, Hyogo 6712280, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo, Kyoto 6158510, Japan
关键词
LIBS; underwater laser-induced breakdown spectroscopy; pulsed laser ablation in liquid; elemental analysis; laser plasma; quantitative spectral analysis; BULK AQUEOUS-SOLUTIONS; OCEANIC PRESSURES INTERRELATIONSHIP; QUANTITATIVE ELEMENTAL ANALYSIS; CALIBRATION-FREE ANALYSIS; DUAL PULSE EXCITATION; COPPER-BASED ALLOYS; INDUCED PLASMA; SINGLE-PULSE; METAL-IONS; SELF-ABSORPTION;
D O I
10.2116/analsci.20R007
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Fundamentals to applications of underwater laser-induced breakdown spectroscopy (LIBS) of submerged solid targets are reviewed. Since the deformation of spectral lines caused by plasma confinement has been the most serious problem in underwater LIBS, the methods developed to overcome this effect are overviewed. Deep-sea LIBS, which is the most successful application of underwater LIBS, is described in some detail as well as the hydrostatic pressure effects. Since the downsizing of underwater LIBS instrument is an important task for the applications to on-site measurements, studies on non-gated LIBS are covered. In the subsequent section, the methods for the quantitative analysis of the underwater LIBS signal are reviewed. The basics of the plasma parameters used in quantitative analysis are explained, and various methods of quantitative analysis applicable to underwater LIBS are described.
引用
收藏
页码:1061 / 1072
页数:12
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