Preparation of High-Octane Oxygenate Fuel Components from Plant-Derived Polyols

被引：72

作者：

Maksimov, A. L. ^{[1
]}

Nekhaev, A. I. ^{[1
]}

Ramazanov, D. N. ^{[1
]}

Arinicheva, Yu. A. ^{[1
]}

Dzyubenko, A. A. ^{[1
]}

Khadzhiev, S. N. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow, Russia

来源：

PETROLEUM CHEMISTRY | 2011年 / 51卷 / 01期

关键词：

O-ISOPROPYLIDENE; GLYCEROL; CATALYST; DERIVATIVES; ZEOLITES; ACID; ACETONATION; CHLORIDE; HY;

D O I：

10.1134/S0965544111010117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ketalization of polyols (glycerol, xylitol, xylose) in the presence of a number of heterogeneous acid catalysts has been studied. It has been shown that zeolite catalysts exhibit high activity in the formation of the acetone ketal of glucose in a flow system with the quantitative selectivity for the 1,2-product. The best catalyst is zeolite beta; in the presence of this zeolite and excess acetone, the yield is over 90% or, in the case of the structured reactor, even greater than 98% It has been shown that zeolite-based systems catalyze the formation of ketals of xylitol and xylose with a yield of up to 50% in the presence of excess acetone.

引用

页码：61 / 69

页数：9

共 48 条

[1] TETRAFLUOROBORIC ACID, AN EFFICIENT CATALYST IN CARBOHYDRATE PROTECTION AND DEPROTECTION REACTIONS [J].

ALBERT, R ;

DAX, K ;

PLESCHKO, R ;

STUTZ, AE .

CARBOHYDRATE RESEARCH, 1985, 137 (MAR) :282-290

[2]

[Anonymous], 2004, US Pat, Patent No. [2004/0 025 417 Al, 025417]

[3]

[Anonymous], 2001, FINE CHEM HETEROGENE

[4]

[Anonymous], 2009, OFF J EUR UNION L, V140

[5]

[Anonymous], BIOREFINERIES IND PR

[6] Clay catalyzed acetonation: A simple method for the preparation of isopropylidene carbohydrates [J].

Asakura, J ;

Matsubara, Y ;

Yoshihara, M .

JOURNAL OF CARBOHYDRATE CHEMISTRY, 1996, 15 (02) :231-239

[7] 1,3-dioxolanes from carbonyl compounds over zeolite HSZ-360 as a reusable, heterogeneous catalyst [J].

Ballini, R ;

Bosica, G ;

Frullanti, B ;

Maggi, R ;

Sartori, G ;

Schroer, F .

TETRAHEDRON LETTERS, 1998, 39 (12) :1615-1618

[8] BEHAVIOR OF ION EXCHANGE RESINS IN SOLVENTS OTHER THAN WATER - SWELLING AND EXCHANGE CHARACTERISTICS [J].

BODAMER, GW ;

KUNIN, R .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1953, 45 (11) :2577-2580

[9]

Bruchmann B., 1999, U.S. Patent, Patent No. [No. US5917059A, 5917059, US Patent 5,917,059]

[10] Synthesis of butyl-α and β-d-glucopyranosides in the presence of dealuminated H-Y faujasites:: Kinetic study, mechanism, stereoelectronic effects, and microreversibility principle [J].

Chapat, JF ;

Finiels, A ;

Joffre, J ;

Moreau, C .

JOURNAL OF CATALYSIS, 1999, 185 (02) :445-453

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